(Cl)(hydrido)(pentamethylcyclopentadienyl)Ir(μ-bis(diphenylphosphino)methane)Ir(pentamethylcyclopentadienyl)Cl2 | 289487-35-0

• 英文名称: (Cl)(hydrido)(pentamethylcyclopentadienyl)Ir(μ-bis(diphenylphosphino)methane)Ir(pentamethylcyclopentadienyl)Cl2
• CAS: 289487-35-0
• 化学式: C₄₅H₅₃Cl₃Ir₂P₂
• 分子量: 1146.66
• InChiKey: DTBUZOZJBZXMTQ-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  (Cl)(hydrido)(pentamethylcyclopentadienyl)Ir(μ-bis(diphenylphosphino)methane)Ir(pentamethylcyclopentadienyl)Cl2 、 silver trifluoromethanesulfonate 以 四氢呋喃 为溶剂， 以79%的产率得到[(pentamethylcyclopentadienyliridium)2(μ-bis(diphenylphosphino)methane)(μ-hydrido)(μ-Cl)][trifluoromethanesulfonate]2
  参考文献：
  名称：

  dppm and hydrido-bridged dinuclear complexes of iridium. Synthesis and structures of [(IrCp*)2(μ-dppm)(μ-H)(μ-X)]2+ (X = Cl, OMe, OH, or H)

  摘要：

  Reaction of [IrCp*Cl(μ-H)]21 (Cp* = pentamethylcyclopentadienyl) with two equivalents of bis(diphenylphosphino)methane (dppm) gave an unidentate dppm complex IrCp*(H)(Cl)(dppm-P) 2. This reacted with a half equivalent of [IrCp*Cl(μ-Cl)]23 to give a dppm-bridged dinuclear complex (Cl)(H)Cp*Ir(μ-dppm)IrCp*Cl24, in which the two metal centers are distal. Reaction of 4 with two equivalents of AgOTf (OTf = O3SCF3) gave a dppm, hydride and chloride-bridged diiridium complex [(IrCp*)2(μ-dppm)(μ-H)(μ-Cl)][OTf]25a. Complex 5a reacted with sodium methoxide in methanol to give [(IrCp*)2(μ-dppm)(μ-H)(μ-OMe)][OTf]26a. This reacted with water in refluxing acetone to give a diiridium complex [(IrCp*)2(μ-dppm)(μ-H)(μ-OH)][OTf]27a. Heating complex 6a in refluxing toluene gave [(IrCp*)2(μ-dppm)(μ-H)2][OTf]28a. The structures of the anion exchanged complexes [(IrCp*)2(μ-dppm)(μ-H)(μ-X)][BPh4]2 [X = Cl 5b, OMe 6b, OH 7b or H 8b] have been confirmed by X-ray analysis.

  DOI：

  10.1039/b001239o
• 作为产物：
  描述：

  双二苯基膦甲烷 、 bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 ((C5(CH3)5)IrCl)2(μ-H)2 以 四氢呋喃 为溶剂， 以85%的产率得到(Cl)(hydrido)(pentamethylcyclopentadienyl)Ir(μ-bis(diphenylphosphino)methane)Ir(pentamethylcyclopentadienyl)Cl2
  参考文献：
  名称：

  dppm and hydrido-bridged dinuclear complexes of iridium. Synthesis and structures of [(IrCp*)2(μ-dppm)(μ-H)(μ-X)]2+ (X = Cl, OMe, OH, or H)

  摘要：

  Reaction of [IrCp*Cl(μ-H)]21 (Cp* = pentamethylcyclopentadienyl) with two equivalents of bis(diphenylphosphino)methane (dppm) gave an unidentate dppm complex IrCp*(H)(Cl)(dppm-P) 2. This reacted with a half equivalent of [IrCp*Cl(μ-Cl)]23 to give a dppm-bridged dinuclear complex (Cl)(H)Cp*Ir(μ-dppm)IrCp*Cl24, in which the two metal centers are distal. Reaction of 4 with two equivalents of AgOTf (OTf = O3SCF3) gave a dppm, hydride and chloride-bridged diiridium complex [(IrCp*)2(μ-dppm)(μ-H)(μ-Cl)][OTf]25a. Complex 5a reacted with sodium methoxide in methanol to give [(IrCp*)2(μ-dppm)(μ-H)(μ-OMe)][OTf]26a. This reacted with water in refluxing acetone to give a diiridium complex [(IrCp*)2(μ-dppm)(μ-H)(μ-OH)][OTf]27a. Heating complex 6a in refluxing toluene gave [(IrCp*)2(μ-dppm)(μ-H)2][OTf]28a. The structures of the anion exchanged complexes [(IrCp*)2(μ-dppm)(μ-H)(μ-X)][BPh4]2 [X = Cl 5b, OMe 6b, OH 7b or H 8b] have been confirmed by X-ray analysis.

  DOI：

  10.1039/b001239o