bis-borohydrido(η-toluene)(trimethylphosphine)2zirconium(II) | 136686-71-0

• 英文名称: bis-borohydrido(η-toluene)(trimethylphosphine)2zirconium(II)
• CAS: 136686-71-0
• 化学式: C₁₃H₃₄B₂P₂Zr
• 分子量: 365.206
• InChiKey: FOROGGMECHRUSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  锂硼氢 、 dichloro(η-toluene)(trimethylphosphine)2zirconium(II) 以 四氢呋喃 为溶剂， 以>80的产率得到bis-borohydrido(η-toluene)(trimethylphosphine)2zirconium(II)
  参考文献：
  名称：

  Convenient one-pot synthesis of half-sandwich η-cycloheptatrienyl and η-toluene derivatives of the metals titanium and zirconium; crystal structure of [Zr(η6-C6H5Me)(PMe3)2Cl2]

  摘要：

  The compounds [M(eta-7-C7H7)L2Cl] (M = Ti; L2 = (PMe3)2, Me2NCH2CH2NMe2, Me2PCH2CH2PMe2. M = Zr; L2 = Me2NCH2CH2NMe2) and the eta-6-arene derivative [Zr(eta-6-C6H5Me)(PMe3)2Cl2] have been prepared in a one-pot reduction of MCl4 in the presence of L2 and an excess of cycloheptatriene or toluene, respectively. The crystal structure of [Zr(eta-6-C6H5Me)(PMe3)2Cl2] has been determined.

  DOI：

  10.1016/0022-328x(91)80070-z