[(3,5-Cl2C6H3NCH2CH2)3N]Ta(η2-ethylene) | 919479-96-2

• 英文名称: [(3,5-Cl2C6H3NCH2CH2)3N]Ta(η2-ethylene)
• CAS: 919479-96-2
• 化学式: C₂₆H₂₅Cl₆N₄Ta
• 分子量: 787.177
• InChiKey: ZRIXAPZKOSLXOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(3,5-Cl2C6H3NCH2CH2)3N]Ta(η2-ethylene) 在 catalyst: C₆H₅PH₂ 作用下， 以 氘代甲苯 为溶剂， 以0%的产率得到[(3,5-Cl2C6H3NCH2CH2)3N]Ta=CHMe
  参考文献：
  名称：

  Synthesis of tantalum and niobium complexes that contain the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2−, and the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3−

  摘要：

  Several niobium and tantalum compounds were prepared that contain either the diamidoamine ligand, [(3,4,5-F3C6H2N-CH2CH2)(2)NMe](2-) ([F3N2NMe](2-)), or the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)(3)N](3-) ([Cl2NNMe](3-)). The former include [F3N2NMe]TaCl3, [F3N2NMe]NbCl3, [F3N2NMe]TaMe3, [F3N2NMe]NbMe3, [(F3N2NMe)TaMe2][MeB(C6F5)(3)], [F3N2NMe]Ta(CHSi-Me-3)(CH2SiMe3), [F3N2NMe]Ta(CH2-t-Bu)Cl-2, [F3N2NMe]Ta(CH-t-Bu)(CHA and [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3). The latter include [ClN2NMe]TaCl2, [Cl2N2NMe]TaMe2, [Cl2NNMe]Ta(eta(2)-C2H4), and [Cl2N2NMe]Ta(eta(2)-C2H2). X-ray diffraction studies were carried out on [F3N2NMe]Ta(CHSiMe3)(CH2SiMe3), [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3) and [Cl2N2NMe]TaMe2.. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.044
• 作为产物：
  描述：

  [(3,5-Cl2C6H3NCH2CH2)3N]TaCl2 、 乙基氯化镁 以 四氢呋喃 为溶剂， 以84%的产率得到[(3,5-Cl2C6H3NCH2CH2)3N]Ta(η2-ethylene)
  参考文献：
  名称：

  Synthesis of tantalum and niobium complexes that contain the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2−, and the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3−

  摘要：

  Several niobium and tantalum compounds were prepared that contain either the diamidoamine ligand, [(3,4,5-F3C6H2N-CH2CH2)(2)NMe](2-) ([F3N2NMe](2-)), or the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)(3)N](3-) ([Cl2NNMe](3-)). The former include [F3N2NMe]TaCl3, [F3N2NMe]NbCl3, [F3N2NMe]TaMe3, [F3N2NMe]NbMe3, [(F3N2NMe)TaMe2][MeB(C6F5)(3)], [F3N2NMe]Ta(CHSi-Me-3)(CH2SiMe3), [F3N2NMe]Ta(CH2-t-Bu)Cl-2, [F3N2NMe]Ta(CH-t-Bu)(CHA and [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3). The latter include [ClN2NMe]TaCl2, [Cl2N2NMe]TaMe2, [Cl2NNMe]Ta(eta(2)-C2H4), and [Cl2N2NMe]Ta(eta(2)-C2H2). X-ray diffraction studies were carried out on [F3N2NMe]Ta(CHSiMe3)(CH2SiMe3), [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3) and [Cl2N2NMe]TaMe2.. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.044