[Mn(2,2'-dpa)(N3)2]2 | 845621-75-2

• 英文名称: [Mn(2,2'-dpa)(N3)2]2
• 英文别名: [Mn(2,2'-dipicolylamine)(N3)2]2
• CAS: 845621-75-2
• 化学式: C₂₄H₂₆Mn₂N₁₈
• 分子量: 676.467
• InChiKey: HVXXNTQBGNCUJD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium azide 、 manganese(II) perchlorate hexahydrate 、 二甲基吡啶胺 以 甲醇 、 水 为溶剂， 以85%的产率得到[Mn(2,2'-dpa)(N3)2]2
  参考文献：
  名称：

  Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)–azido complex: [Mn(2,2′-dpa)(N3)2]2 (2,2′-dpa=2,2′-dipicolylamine)

  摘要：

  A new dinuclear manganese(II)-azido complex: [Mn(2,2'-dpa)(N-3)(2)](2) 1 (2,2'-dpa = 2,2'-dipicolylamine) has been synthesized solvothermally. X-ray crystallography analysis reveals that it consists of two crystallographically independent dimeric manganese moieties; each manganese(II) atom is coordinated by one 2,2'-dipicolylamine, one terminal azido ligand, and double end-on bridging azido ligands, exhibiting a slightly distorted octahedral sphere. There are extensive short contacts among dimeric manganese moieties, which extend the structure into an interesting three-dimensional supramolecular array. Magnetic determination of 1 indicates that dominant ferromagnetic interaction and weak antiferromagnetic interaction, which are ascribed to the end-on azido bridges and the short contacts, respectively, co-exist in this complex. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.043