(kappa.3-N,N',N''-hydrotris(pyrazolyl)borate)Rh(PMe3)(H)2 | 381223-64-9

• 英文名称: (kappa.3-N,N',N''-hydrotris(pyrazolyl)borate)Rh(PMe3)(H)2
• CAS: 381223-64-9
• 化学式: C₁₂H₂₁BN₆PRh
• 分子量: 394.029
• InChiKey: FVOZGJILUJTAFI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (kappa.3-N,N',N''-hydrotris(pyrazolyl)borate)Rh(PMe3)(H)2 、 三甲基膦 以 四氢呋喃 为溶剂， 以40%的产率得到(kappa.0-hydrotris(pyrazolyl)borate)Rh(PMe3)2(H)2
  参考文献：
  名称：

  Denticity Changes of Hydrotris(pyrazolyl)borate Ligands in RhI and RhIII Compounds: Fromκ3- to Ionic “κ0”-Tp′

  摘要：

  Isolated hydrotris(pyrazolyl)borate anions Tp' were obtained as salts of metal complex cations (see picture) by the displacement of Rh-coordinated kappa(3)-N,N',N"-Tp' by PMe(3) (Tp'=Tp and Tp(Me2)). With [(kappa(3)-Tp(Me2))Rh(C(2)H(4))(2)], stepwise diplacement of the Tp(Me2) ligand allowed the isolation of complexes exhibiting the kappa(2)- Tp(Me2) and kappa(1)-Tp(Me2) coordination modes.

  DOI：

  10.1002/(sici)1521-3773(20000103)39:1<218::aid-anie218>3.0.co;2-f