Cu2(bpy)2(phga)4 | 870462-73-0

• 英文名称: Cu2(bpy)2(phga)4
• 英文别名: Cu2(2,2'-bipyridine)2(phenylglyoxylic acid(-H))4
• CAS: 870462-73-0
• 化学式: C₅₂H₃₆Cu₂N₄O₁₂
• 分子量: 1035.97
• InChiKey: HNDSAERNHVWQIE-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 copper(II) methoxide 、 苯甲酰甲酸 以 乙腈 为溶剂， 以73%的产率得到Cu2(bpy)2(phga)4
  参考文献：
  名称：

  Synthesis, structure and catalase-like activity of new dicopper(II) complexes with phenylglyoxylate and benzoate ligands

  摘要：

  The preparation and characterization of dimeric Cu-2(bpy)(2)(phga)(4) (bpy: 2,2'-bipyridine; phgaH: phenylglyoxylic acid) and Cu-2(ba)(4)(bpy)(2) (baH: benzoic acid) complexes are described. Crystallographic characterization of the Cu-2(bpy)(2)(phga)(4) complex has shown that the coordination geometry around copper(II) ions is distorted square pyramidal (monoclinic, P21/c, a=11.7440(4)angstrom, b = 20.9020(10) angstrom, c = 9.3980(10) angstrom, alpha=90.00 degrees, beta=93.2240(10)degrees, gamma=90.00 degrees, V=2303.3(3) angstrom(3), Z=4). These complexes were found to exhibit catalase-like activity. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.04.006
• 作为试剂：
  描述：

  双氧水 在 Cu2(bpy)2(phga)4 作用下， 以 乙腈 为溶剂， 生成 氧气
  参考文献：
  名称：

  Synthesis, structure and catalase-like activity of new dicopper(II) complexes with phenylglyoxylate and benzoate ligands

  摘要：

  The preparation and characterization of dimeric Cu-2(bpy)(2)(phga)(4) (bpy: 2,2'-bipyridine; phgaH: phenylglyoxylic acid) and Cu-2(ba)(4)(bpy)(2) (baH: benzoic acid) complexes are described. Crystallographic characterization of the Cu-2(bpy)(2)(phga)(4) complex has shown that the coordination geometry around copper(II) ions is distorted square pyramidal (monoclinic, P21/c, a=11.7440(4)angstrom, b = 20.9020(10) angstrom, c = 9.3980(10) angstrom, alpha=90.00 degrees, beta=93.2240(10)degrees, gamma=90.00 degrees, V=2303.3(3) angstrom(3), Z=4). These complexes were found to exhibit catalase-like activity. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.04.006