[Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)] | 667938-05-8

• 英文名称: [Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)]
• 英文别名: [Ru(bdmpzsa)(en)(Cl)]
• CAS: 667938-05-8
• 化学式: C₁₃H₂₃ClN₆O₃RuS
• 分子量: 479.953
• InChiKey: DVUOBXAERYUXLY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4 、 三氯化钌 、 乙二胺 以 甲醇 为溶剂， 以88%的产率得到[Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)]
  参考文献：
  名称：

  Interaction of ruthenium(III) chloride with bis(3,5-dimethylpyrazol-1-yl)methane oxyanions, potential κ3-N,N,O scorpionates

  摘要：

  When RuCl3 was set to react with both bis(3,5-dimethylpyrazol-1-yl) acetate (bdmpza) and bis(3,5-dimethylpyrazol-1-yl)methane sulfonate (bdmpzsa) new ruthenium(II) complexes were obtained. The reduction of ruthenium(III) was studied by the NMR Evans method and spectrophotometrically, for 1:1 (Ru:L) molar ratios. Using the Evans method pseudo first-order constants of 2.5 x 10(-3) s(-1) (bdmpzsa) and 3.9 x 10(-3) s(-1) (bdmpza) were obtained in DMSO-d(6) (2% t-butanol) solutions. Spectrophotometrically the corresponding constants were also calculated: 1.1 x 10(-3) s(-1) for bdmpzsa, and 1.6 x 10(-3) s(-1), for bdmpza. Both ligands behave as kappa(3)-N,N,O scorpionates but with a weak oxyanionic coordination to the metal, susceptible to be substituted with NEt3 for a 1:1 molar ratio. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00437-7