[Pd(2ppy*)(2,6-dimethylpyridine)Cl] | 155418-15-8

• 英文名称: [Pd(2ppy*)(2,6-dimethylpyridine)Cl]
• 英文别名: [Pd(2ppy*)(2,6-lutidine)Cl]；[Pd(2ppy*)(2,6lut)Cl]；a-chloro-b-(2'',6''-dimethylpyridine-N'')-dc-[2-(2'-pyridyl)phenyl-N',C]palladium
• CAS: 155418-15-8
• 化学式: C₁₈H₁₇ClN₂Pd
• 分子量: 403.219
• InChiKey: YZIQKIYGPIYIAX-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  2,6-二甲基吡啶 、 di-μ-chlorobis{(2-phenylpyridine)palladium(II)} 以 丙酮 为溶剂， 生成 [Pd(2ppy*)(2,6-dimethylpyridine)Cl]
  参考文献：
  名称：

  Structural and 1H, 13C, 15N NMR spectroscopic studies of Pd(II) chloride organometallics with 2-phenylpyridine and ammonia, pyridine or its methyl derivatives

  摘要：

  Pd(II) chloride organometallics with 2-phenylpyridine and pyridines of general formula [Pd(2ppy*)LCl] (2ppy* = C(2')-deprotonated form of 2-phenylpyridine (2ppy), acting as N(1),C(2')-chelating ligand; L = NH3, pyridine, 2-, 3-, 4-methylpyridine, 2,3-, 2,4-, 2,6-, 3,5-dimethylpyridine, 2,4,6-trimethylpyridine) were studied by H-1, C-13 and N-15 NMR. H-1, C-13 and N-15 NMR coordination shifts (i.e. differences of chemical shifts for the same atom in the complex and ligand molecules) were discussed in relation to the molecular structures. Single crystal X-ray structure of trans(N,N)-[Pd(2ppy*)(2,4,6col)Cl] was solved. The analysis of 15N NMR coordination shifts for the whole series of the studied organometallics exhibited that all of them had an analogous trans(N,N) geometry. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.02.028