[η5-1,2,3,3a,7a-(6-bromoindenyl)-η5-cyclopentadienyl]iron | 873785-68-3

• 英文名称: [η5-1,2,3,3a,7a-(6-bromoindenyl)-η5-cyclopentadienyl]iron
• CAS: 873785-68-3
• 化学式: C₁₄H₁₁BrFe
• 分子量: 314.992
• InChiKey: QHTFXTBUYOMTEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [η5-1,2,3,3a,7a-(6-bromoindenyl)-η5-cyclopentadienyl]iron 、 六羰基铬 、 三氟甲烷磺酸甲酯 在 tert-butyllithium 作用下， 以 乙醚 、 正戊烷 为溶剂， 以63%的产率得到pentacarbonyl[(η5-1,2,3,3a,7a-indenyl-η5-cyclopentadienyl)iron-(methoxy)-carbene]chromium
  参考文献：
  名称：

  Reactions of complex ligands part 106. Heterobimetallic fused arenes: Chromium-templated benzannulation of a ferrocene-type metal carbene

  摘要：

  The heterobimetallic iron cyclopentadienyl(indenyl)carbene chromium complex 3 was synthesized from 5-bromoindene by via metalation with C5H5Fe(CO)(2)I, photodecarbonylation and chromium carbene functionalization of the pi-bromoindenyl(cyclopentadienyl)iron intermediate 2. The chromium-templated benzannulation with 3-hexyne afforded syn- and anti-diastereomers of heterobimetallic hydroquinoid arene Cr(CO)(3) complexes 4a and 4b which were characterized by X-ray, spectroscopic and electrochemical means. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.07.081
• 作为产物：
  描述：

  [(η5-cyclopentadienyl)(CO)2(C9H6Br)] 以 petroleum ether 为溶剂， 生成 [η5-1,2,3,3a,7a-(6-bromoindenyl)-η5-cyclopentadienyl]iron
  参考文献：
  名称：

  Reactions of complex ligands part 106. Heterobimetallic fused arenes: Chromium-templated benzannulation of a ferrocene-type metal carbene

  摘要：

  The heterobimetallic iron cyclopentadienyl(indenyl)carbene chromium complex 3 was synthesized from 5-bromoindene by via metalation with C5H5Fe(CO)(2)I, photodecarbonylation and chromium carbene functionalization of the pi-bromoindenyl(cyclopentadienyl)iron intermediate 2. The chromium-templated benzannulation with 3-hexyne afforded syn- and anti-diastereomers of heterobimetallic hydroquinoid arene Cr(CO)(3) complexes 4a and 4b which were characterized by X-ray, spectroscopic and electrochemical means. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.07.081