6-ferrocenyl-11-methyl-4,5,11-triazatricyclo[6.2.1.0(3,7)]undec-3-ene | 356041-22-0

• 英文名称: 6-ferrocenyl-11-methyl-4,5,11-triazatricyclo[6.2.1.0(3,7)]undec-3-ene
• CAS: 356041-22-0
• 化学式: C₁₉H₂₃FeN₃
• 分子量: 349.259
• InChiKey: KCPUWLJYKNCSBX-HKTVSDORSA-N

反应信息

• 作为反应物：
  描述：

  6-ferrocenyl-11-methyl-4,5,11-triazatricyclo[6.2.1.0(3,7)]undec-3-ene 、 乙酸酐 在 Na₂CO₃ 作用下， 以 乙酸酐 为溶剂， 以69%的产率得到5-acetyl-6-ferrocenyl-11-methyl-4,5,11-triazatricyclo[6.2.1.0(3,7)]undec-3-ene
  参考文献：
  名称：

  摘要：

  The reactions of E- and Z-isomeric 2-(ferrocenylmethylidene)quinuclidin-3-one, 1-methyl-3-(ferrocenylmethylidene)piperidin-4-one, and 2-(ferrocenylmethylidene)tropinone with hydrazine proceed stereospecifically to form the same diastereomeric polycyclic ferrocenyldihydropyrazoles regardless of the geometrical configuration of the starting alpha,beta -unsaturated ketones. The structure of the trans-diastereomer of 4-acetyl-3-ferrocenyl-1,4,5-triazatricyclo[5.2.2.0(2,6)]undec-5-ene was established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1011375613460
• 作为产物：
  描述：

  E-2-(ferrocenylmethylidene)-8-azabicyclo[3.2.1]octan-3-one 、 一水合肼 以 乙醇 为溶剂， 以71%的产率得到6-ferrocenyl-11-methyl-4,5,11-triazatricyclo[6.2.1.0(3,7)]undec-3-ene
  参考文献：
  名称：

  摘要：

  The reactions of E- and Z-isomeric 2-(ferrocenylmethylidene)quinuclidin-3-one, 1-methyl-3-(ferrocenylmethylidene)piperidin-4-one, and 2-(ferrocenylmethylidene)tropinone with hydrazine proceed stereospecifically to form the same diastereomeric polycyclic ferrocenyldihydropyrazoles regardless of the geometrical configuration of the starting alpha,beta -unsaturated ketones. The structure of the trans-diastereomer of 4-acetyl-3-ferrocenyl-1,4,5-triazatricyclo[5.2.2.0(2,6)]undec-5-ene was established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1011375613460