4',5,7-trihydroxy-6-(tricarbonyl[(1'',2'',3'',4''-η)-1'',3''-cyclohexadien-5''α-yl]iron(0))flavanone | 220433-57-8

• 英文名称: 4',5,7-trihydroxy-6-(tricarbonyl[(1'',2'',3'',4''-η)-1'',3''-cyclohexadien-5''α-yl]iron(0))flavanone
• CAS: 220433-57-8
• 化学式: C₂₄H₁₈FeO₈
• 分子量: 490.249
• InChiKey: FZYWRNOGRNGQLB-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tricarbonyl[(1,2,3,4,5-η)-1,3-cyclohexadienyl]iron(1+) hexafluorophosphate(1-) 、 柚皮素 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 以88%的产率得到4',5,7-trihydroxy-6-(tricarbonyl[(1'',2'',3'',4''-η)-1'',3''-cyclohexadien-5''α-yl]iron(0))flavanone
  参考文献：
  名称：

  Attachment of IR-active organometallic probe groups to flavonoid inducers of nod gene expression

  摘要：

  Direct reaction of flavanones with electrophilic tricarbonyl[(1,2,3,4, 5-eta)cyclohexadienyliron(1+) complexes affords organometallic derivatives for use as probes of molecular recognition events during the induction of nodulation genes in Rhizobium leguminosarum. A more selective preparation method has been developed by deprotonation of the flavanone prior to the addition of the cyclohexadienyliron complex. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00398-8