FeBd2(Gm)(BF)2 | 220227-60-1

• 英文名称: FeBd2(Gm)(BF)2
• 英文别名: Fe(α-benzyldioximato)2(glyoximato)(BF)2
• CAS: 220227-60-1
• 化学式: C₃₀H₂₂B₂F₂FeN₆O₆
• 分子量: 678.007
• InChiKey: GUKFXSLKBBDPHD-CJCMDRELSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Fe((difluoroboryl)diphenylglyoximate)(MeCN)2 、 乙二肟 在 N,N-diisopropylethylamine 、 BF₃ * O(C₂H₅)2 作用下， 以 乙腈 为溶剂， 以14%的产率得到FeBd2(Gm)(BF)2
  参考文献：
  名称：

  Synthesis, spectral and electrochemical characteristics of asymmetrical iron(II) tris-dioximates

  摘要：

  Meridianal- and axial-asymmetrical clathrochelate tris-dioximates of the FeD2D'(BF)(2) and FeD3(BX)(Y) types (where D,D' = dioximes dianions, X = C6H5, F; Y = BF, Bn-C4H9, SnCl3) have been prepared by a stepwise synthesis from a planar-square macrocyclic precursors in the first case and from a semiclathrochelate compounds immobilized on the sorbent surface in the second one. The composition and structure of the isolated compounds have been established from elemental analysis data, polynuclear NMR, Fe-57 Mossbauer and FAB mass spectra. The structure parameters of alpha-benzyldioximate FeBd(3)(BF)(Bn-C4H9) . C6H5CH3 . 1/2C(8)H(16) (Fe-N distance - 1.89 Angstrom, bite angle - 38.6 degrees, polyhedron distortion angle - 17.9 degrees) were determined by X-ray crystallography, The electrochemical properties of the obtained complexes and their dependence on the nature of a ligand have been determined by cyclic voltammetry. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00168-5