[bis(triphenylphosphonium)iminium][Fe3(CO)9(CCH)] | 220829-92-5

• 英文名称: [bis(triphenylphosphonium)iminium][Fe3(CO)9(CCH)]
• CAS: 220829-92-5
• 化学式: C₁₁HFe₃O₉*C₃₆H₃₀NP₂
• 分子量: 983.253
• InChiKey: XURQPBQUGGSDCW-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [bis(triphenylphosphonium)iminium][Fe3(CO)9(CCH)] 在 triflic acid 作用下， 以 四氢呋喃 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  [PPN][Fe₃(CO)₉(C⋮CH)] and [Fe₃(CO)₉(C⋮COTi(THF)₄Cl)] from the Reaction of Low-Valent Titanium with [Fe₃(CO)₉(CCO)]^2-

  摘要：

  TiCl3(DME)(1.5) (DME = 1,2-dimethoxyethane) and a Zn-Cu couple react with [PPN](2)[Fe-3(CO)(9)(CCO)] to give the new compound [PPN][Fe-3(CO)(9)(C drop CH)] (I) (70% yield), a known compound [Fe-3(CO)(10)(CCH2)] (II) (9% yield), and another new compound [Fe-3(CO)(9)(CCOTi-(THF)(4)Cl)] (III). Compound I was characterized by H-1 and C-13 NMR, IR, mass spectrometry, and X-ray crystallography. Compound III was characterized by IR, mass spectrometry, C-13 NMR, and X-ray crystallography.

  DOI：

  10.1021/om9806085
• 作为产物：
  描述：

  TiCl3(1,2-dimethoxyethane)1.5 、 Fe3(CO)9(μ3-ketenylidene)(2-), bis(triphenylphosphine)nitrogen(1+) salt 在 Zn-Cu 作用下， 以 四氢呋喃 、 乙二醇二甲醚 为溶剂， 以70%的产率得到[bis(triphenylphosphonium)iminium][Fe3(CO)9(CCH)]
  参考文献：
  名称：

  [PPN][Fe₃(CO)₉(C⋮CH)] and [Fe₃(CO)₉(C⋮COTi(THF)₄Cl)] from the Reaction of Low-Valent Titanium with [Fe₃(CO)₉(CCO)]^2-

  摘要：

  TiCl3(DME)(1.5) (DME = 1,2-dimethoxyethane) and a Zn-Cu couple react with [PPN](2)[Fe-3(CO)(9)(CCO)] to give the new compound [PPN][Fe-3(CO)(9)(C drop CH)] (I) (70% yield), a known compound [Fe-3(CO)(10)(CCH2)] (II) (9% yield), and another new compound [Fe-3(CO)(9)(CCOTi-(THF)(4)Cl)] (III). Compound I was characterized by H-1 and C-13 NMR, IR, mass spectrometry, and X-ray crystallography. Compound III was characterized by IR, mass spectrometry, C-13 NMR, and X-ray crystallography.

  DOI：

  10.1021/om9806085