[(η(5)-C5H5)W(CO)3(C(O)-n-C11H23)] | 223921-15-1

• 英文名称: [(η(5)-C5H5)W(CO)3(C(O)-n-C11H23)]
• CAS: 223921-15-1
• 化学式: C₂₀H₂₈O₄W
• 分子量: 516.29
• InChiKey: GWSAHRYSGRKYGK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  月桂酰氯 、 bis(tricarbonyl(η-cyclopentadienyl)tungsten) 在 sodium amalgam 作用下， 以 四氢呋喃 为溶剂， 以52%的产率得到[(η(5)-C5H5)W(CO)3(C(O)-n-C11H23)]
  参考文献：
  名称：

  Synthesis and characterization of long chain acyl and alkyl complexes of the types [(η5-C5R′5)Fe(CO)2{C(O)R}] (R′=H, CH3), [CpW(CO)3{C(O)R}] and [CpW(CO)3R] (R=n-alkyl)

  摘要：

  The long chain acyl complexes [CpFe(CO)(2){C(O)R}] (R = n-C5H11, n-C8H17, n-C11H23, and n-C17H35), [Cp*Fe(CO)(2){C(O)C11H23}] and [CpW(CO)(3){C(O)C11H23}] have been prepared by the reactions of Na[CpFe(CO)(2)], Na[CpFe(CO)(2)] and Na[CpW(CO)(3)], respectively, with the appropriate acyl chlorides. Some new alkyl complexes [CpW(CO)(3)R] (R = n-C6H13, n-C7H15, and n-C8H17) have been prepared by the reactions of Na[CpW(CO)(3)] with the appropriate alkyl bromide or iodide. All of these complexes have been characterized by microanalysis, IR, H-1 and C-13 NMR and mass spectroscopy. The thermal behavior of some acyl complexes has also been investigated by differential scanning calorimetry and thermal gravimetric analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00388-0