| 228553-92-2

• CAS: 228553-92-2
• 化学式: C₁₃H₃₁B₃
• 分子量: 219.822
• InChiKey: QFZGDLJWYSLIQP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 碘甲烷 以 四氢呋喃 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  2,3,5-Tri-tert-butyl-1-carba-nido-tetraborane

  摘要：

  The missing link in the series of tert-butyl derivatives of the isoelectronic nido clusters B4 H8 , CB3 H7 , and NB3 H6 with a bicyclobutane-type structure is represented by the title compound CB3 H4 tBu3 (1), the clusters B4 H4 tBu4 and NB3 H3 tBu3 being well known. Compound 1 may also be considered to be a derivative of the nido-triborane B3 H7 , which has hitherto not been isolated, formed by replacing three H atoms by tBu groups and two H atoms by a CH2 bridge, as expressed by the formula B3 H2 tBu3 (CH2 ).

  DOI：

  10.1002/(sici)1521-3773(19990503)38:9<1281::aid-anie1281>3.0.co;2-a