| 257950-16-6

• CAS: 257950-16-6
• 化学式: C₂₈H₂₃Mo₂O₄P
• 分子量: 646.342
• InChiKey: FAOODNWSRMVMFO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (Mo2(η5-C5H5)2(μ-H)(μ-PPhH)(CO)4) 、 丙烯酰氯 在 tBuLi 作用下， 以 not given 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Reactivity of acryloyl chloride towards the anion [Cp2(CO)4Mo2(μ-PPhH)]−; synthesis of an unusual phosphaalkene

  摘要：

  Deprotonation of the complex [Cp2(CO)4Mo2(µ-PPhH)(µ-H)] by ButLi at –78 °C and subsequent addition of acryloyl chloride affords the metallophosphaalkene complex [Cp2(CO)4Mo2(η1-η2-PhPCHMe)] in high yield; the complex exhibits cis/trans isomerism, both isomers having been crystallographically characterised.

  DOI：

  10.1039/a907915g