[AuCl(N(p-C6H4COOEt))] | 1208219-68-4

• 英文名称: [AuCl(N(p-C6H4COOEt))]
• CAS: 1208219-68-4
• 化学式: C₁₀H₉AuClNO₂
• 分子量: 407.606
• InChiKey: GUKWCKQFDFBEBU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [AuCl(N(p-C6H4COOEt))] 、 二乙胺 以 CH₂Cl₂ 为溶剂， 以98%的产率得到[AuCl(CNH(p-C6H4COOEt)(NEt2))]
  参考文献：
  名称：

  Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

  摘要：

  Complexes [AuCl{C(NHR)(NHR')}] and [AuCl{C(NHR)(NEt2)}] (R =Bu-t, p-Tol, Xylyl, p-C6H4-COOH, p-C6H4COOEt, R' = Me, Bu-n, Pr-i, (n)heptyl, p-Tol) have been prepared by reaction of the corresponding isocyanogold complexes [AuCl(CNR)] with either primary amines or diethylamine. All the prepared carbenes are reactive and highly selective catalysts for skeletal rearrangement, methoxycyclization of 1,6-enynes, and other mechanistically related gold-catalyzed transformations. Overall, these easily accessible nitrogen acyclic carbene (NAC) gold complexes were not second to NHC complexes and were advantageous to obtain different products.

  DOI：

  10.1021/om901026m
• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 ethyl 4-isocyanobenzoate 以 not given 为溶剂， 生成 [AuCl(N(p-C6H4COOEt))]
  参考文献：
  名称：

  Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

  摘要：

  Complexes [AuCl{C(NHR)(NHR')}] and [AuCl{C(NHR)(NEt2)}] (R =Bu-t, p-Tol, Xylyl, p-C6H4-COOH, p-C6H4COOEt, R' = Me, Bu-n, Pr-i, (n)heptyl, p-Tol) have been prepared by reaction of the corresponding isocyanogold complexes [AuCl(CNR)] with either primary amines or diethylamine. All the prepared carbenes are reactive and highly selective catalysts for skeletal rearrangement, methoxycyclization of 1,6-enynes, and other mechanistically related gold-catalyzed transformations. Overall, these easily accessible nitrogen acyclic carbene (NAC) gold complexes were not second to NHC complexes and were advantageous to obtain different products.

  DOI：

  10.1021/om901026m