fac-[Mn(1,10-phenanthroline)(CO)3(imidazole)]trifluoromethanesulfonate | 266337-88-6

• 英文名称: fac-[Mn(1,10-phenanthroline)(CO)3(imidazole)]trifluoromethanesulfonate
• 英文别名: fac-[(imidazole)(1,10-phenanthroline)tricarbonylmanganese(I)] triflate
• CAS: 266337-88-6
• 化学式: CF₃O₃S*C₁₈H₁₂MnN₄O₃
• 分子量: 536.327
• InChiKey: IRLSXVCECIUFNC-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  咪唑 、 [Mn(CO)3(1,10-phenanthroline)(CF3SO3)] 以 二氯甲烷 为溶剂， 以90%的产率得到fac-[Mn(1,10-phenanthroline)(CO)3(imidazole)]trifluoromethanesulfonate
  参考文献：
  名称：

  探索负责循环电子转移诱导异构体因子的电子因子：fac- [Mn（CO）3（L'–L'）L] 0 / +配合物的合成，电化学和光谱研究

  摘要：

  摘要fac- [Mn（CO）3（L′–L′）（L）] 0 / +的光谱（IR，31P NMR和UV-Vis）和电化学研究，其中L′–L′= 1,2-采取双（二苯基膦基）乙烷（dppe）或1,10-菲咯啉（phen）和L =溴化物，三氟甲磺酸盐，咪唑（im），异烟酰胺（isn）或N-（2-羟乙基）异烟酰胺（heisn）各种配体对这些配合物的CO–Mn–L和CO–Mn–（L'–L'）键合特征的影响。报告了L = triflate / L'–L'= dppe，L = triflate / L'–L'= phen和L = is / L'–L'= phen的晶体结构，它们显示了两个Mn–O（ OSO2CF3）和Mn–N（isn）的距离相似。三羰基配合物在UV-Vis光谱的250-300和350-450 nm区域显示两个主要谱带。最低能带被指定为金属中心（MC）和金属到配体（dπ→L'–L'）电荷转移

  DOI：

  10.1016/j.ica.2005.07.012

文献信息

• Spectroscopic and electrochemical properties of [Mn(phen)(CO)3(imidazole)](SO3CF3) complexes
  作者：Rose Maria Carlos、Ivani Ap. Carlos、Benedito S.Lima Neto、Miguel G. Neumann

  DOI：10.1016/s0020-1693(99)00505-8

  日期：2000.3

  The spectroscopic and electrochemical properties of [Mn(phen)(CO)(3)(L)](+) type complexes where L is an imidazole or an imidazole derivative containing a methyl, phenyl or NO, group, have been investigated, introduction of the substituents to the cr-donor ligand has been found to produce significant changes in the electrochemical behaviour without significantly altering the fundamental electronic structure of the complexes. The oxidation potentials of the fac-[Mn(phen)(CO)(3)L](+) and mer-[Mn-(phen)(CO)(3)L](+) isomers are very different, allowing detailed electrochemical studies to be made. Cyclic voltammetry of both the fac and mer isomers provides a complete description of a cyclic process involving the following reactions.[GRAPHICS](C) 2000 Elsevier Science S.A. All rights reserved.