tert-butyl [(ferrocenyl)(dimethyl(phenyl)silyl)]methyl sulphide | 401513-11-9

• 英文名称: tert-butyl [(ferrocenyl)(dimethyl(phenyl)silyl)]methyl sulphide
• CAS: 401513-11-9
• 化学式: C₂₃H₃₀FeSSi
• 分子量: 422.49
• InChiKey: UGXMHHDKLNZSNM-ZEECNFPPSA-N

反应信息

• 作为产物：
  描述：

  cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-yl-[dimethyl(phenyl)silyl]methanethione;iron(2+) 、 叔丁基锂 以 四氢呋喃 为溶剂， 以78%的产率得到tert-butyl [(ferrocenyl)(dimethyl(phenyl)silyl)]methyl sulphide
  参考文献：
  名称：

  Synthesis and reactivity of achiral and of a novel planar chiral thioferrocenoylsilanes

  摘要：

  The reactions of thioferrocenoylsilanes with organolithium reagents, dienes and reducing agents which afford alpha -silyl sulphides, dihydrothiopyranes and alpha -silyl ferrocenyl thiols, respectively, have been investigated. alpha -Silyl sulphides were further functionalised through carbodesilylation with aldehydes. We also report the synthesis of a new planar chiral thioferrocencylsilane that gave good diastereomeric excess in the reaction with t-butyllithium, lithium lutidine and 2,3-dimethylbuta-1,3-diene. The 1,1'-bis-thioferrocenoylsilane, too unstable to be isolated, was trapped in situ with dienes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00944-5