di-μ-cyanobis{tetracyanoferrate(III)} | 23411-57-6

• 英文名称: di-μ-cyanobis{tetracyanoferrate(III)}
• 英文别名: di-μ-cyano-bis[tetracyanoferrate(III)](4-)
• CAS: 23411-57-6
• 化学式: C₁₀Fe₂N₁₀
• 分子量: 371.871
• InChiKey: VQQVXCRLAINKPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  di-μ-cyanobis{tetracyanoferrate(III)} 在 thiosulfate(2-) 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Redox chemistry of [Fe₂(CN)₁₀]^4–. Part 2. Reaction with thiosulfate

  摘要：

  The oxidation of thiosulfate by the iron(III) dimeric complex [Fe2(CN)10]4- in acidic aqueous solution at an ionic strength of 1.0 mol dm-3 (Na2SO4) has been investigated by stopped-flow and conventional spectrophotometry. The overall reaction is quite complicated, occurring in two distinct processes. The first comprises two steps, involving an intermediate, and results in a relatively fast one-electron reduction to [Fe2(CN)10]5-, the rate of which was monitored by the stopped-flow technique; this is followed by a much slower second reaction leading to fission of the cyanide bridges and the formation of the pentacyano(thiosulfato)ferrate-(II) and -(III) complexes. Separate mechanisms are given for each step based on the observed kinetic data.

  DOI：

  10.1039/dt9930003605

文献信息

• Reaction of [Fe2(CN)10]4? with L-ascorbic acid
  作者：Floyd A. Beckford、Tara P. Dasgupta、Geoffrey Stedman

  DOI：10.1039/dt9950002561

  日期：——

  studied. The mechanisms for both stages of the reaction are similar and involve formation of an ion triplet [Fe2(CN)10]n–·M+·Ap– where n= 4 or 5 and Ap– is the reacting ascorbate species with p= 1 or 2. The rate law was found to be of the form (i) where [A]T is the total concentration of added ascorbate, k1 and k2 the acid dissociation constants Rate =k′K1[H+]+k″K1K2//K1K2+K1[H+]+[H+]2[A]T[complex](i), of

  通过停止流动研究了铁（III）二聚配合物[Fe 2（CN）10 ] 4–在酸性水溶液中在离子强度为1.0 mol dm –3（NaClO 4）的条件下对L-抗坏血酸的氧化作用。分光光度法。总的反应，这需要两个还原的铁（III）的中心，随后导致2摩尔的形成水合作的[Fe（CN）5（OH 2）] 3-，发生在三个阶段。首先是单电子还原以形成混合价铁（III，II）二聚体，然后第二个电子再还原另一个铁（III）中心，形成铁（II）二聚体。没有研究吸光度变化很小的第三阶段。反应两个阶段的机理都相似，涉及形成离子三重态[Fe 2（CN）10 ] n – ·M + ·A p –，其中n = 4或5，A p –是与抗坏血酸发生反应的物质。p = 1或2。发现速率定律的形式为（i），其中[A] T是添加的抗坏血酸盐的总浓度k 1和k 2酸解离常数Rate =ķ ' ķ 1 [H + ] + ķ “ ķ 1