[(η5:η1-2,4-Me2-C5H2CO2CH2CH2PPh2)Ru(triphenylphosphite)(tert-butyl isocyanide)][PF6] | 854648-49-0

• 英文名称: [(η5:η1-2,4-Me2-C5H2CO2CH2CH2PPh2)Ru(triphenylphosphite)(tert-butyl isocyanide)][PF6]
• CAS: 854648-49-0
• 化学式: C₄₅H₄₆NO₅P₂Ru*F₆P
• 分子量: 988.846
• InChiKey: ZFUDTXMTRLWBJN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  异氰酸叔丁酯 、 [(η5:η1-2,4-Me2-C5H2CO2CH2CH2PPh2)Ru(triphenylphosphite)(acetonitrile)][PF6] 以 1,2-二氯乙烷 为溶剂， 以85%的产率得到[(η5:η1-2,4-Me2-C5H2CO2CH2CH2PPh2)Ru(triphenylphosphite)(tert-butyl isocyanide)][PF6]
  参考文献：
  名称：

  Diastereoselective Formation of Ruthenium-Isocyanide and -Acetylide Complexes with Planar-Chiral Cyclopentadienyl-Phosphine Ligands

  摘要：

  The reaction of ruthenium complexes [(eta(5):eta(1)-2-Me-4-R-C5H2CO2CH2CH2PPh2)Ru(PR'(3))(NCMe)] [PF6] (R = Me, Ph, Bu-t; R'= Ph, Me, OPh) possessing planar-chiral cyclopentadienyl-phosphine ligands with tert-butyl isocyanide resulted in the diastereoselective formation of ruthenium-isocyanide complexes (up to > 99% de) under kinetic control. The reaction with phenylacetylene followed by treatment with alumina gave acetylide complexes diastereoselectively (up to > 99% de). The configuration of the products was determined by X-ray analyses as well as NOE measurements. In both reactions, the stereochemistry of the ruthenium atom in the substrate did not influence the diastereoselectivity of the products, although the substituent on the cyclopentadienyl ring and the phosphorus ligands on the ruthenium atom showed steric effects on the selectivity.

  DOI：

  10.1021/om0500523