| 680987-55-7

• CAS: 680987-55-7
• 化学式: C₂₀H₁₄N₂O₆Rh₃*C₃₆H₃₀NP₂
• 分子量: 1225.65
• InChiKey: FHIZZKXPDKHFIQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 (FeCp₂)PF₆ 作用下， 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Bi-edge condensation of imido–rhodium clusters leading to novel planar hexametallic structures

  摘要：

  Oxidation of [N(PPh3)2][Rh3(µ-NC6H4Me-p)2(CO)6] with [FeCp2]PF6 gives the novel hexarhodium compound [{Rh3(µ-NC6H4Me-p)2(CO)6}2], containing three nearly coplanar condensed metallic cycles forming a doubly-spiked square, by dimersisation of the trinuclear imidocomplex through the formation of unsupported metal–metal bonds.

  DOI：

  10.1039/a907853c
• 作为产物：
  描述：

  、 双(三苯基正膦基)氯化铵 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Bi-edge condensation of imido–rhodium clusters leading to novel planar hexametallic structures

  摘要：

  Oxidation of [N(PPh3)2][Rh3(µ-NC6H4Me-p)2(CO)6] with [FeCp2]PF6 gives the novel hexarhodium compound [{Rh3(µ-NC6H4Me-p)2(CO)6}2], containing three nearly coplanar condensed metallic cycles forming a doubly-spiked square, by dimersisation of the trinuclear imidocomplex through the formation of unsupported metal–metal bonds.

  DOI：

  10.1039/a907853c