bis-palladium-bis (μ-acetato)-3,6-bis(4'-butyloxyphenyl)pyridazine | 373387-84-9

• 英文名称: bis-palladium-bis (μ-acetato)-3,6-bis(4'-butyloxyphenyl)pyridazine
• CAS: 373387-84-9
• 化学式: C₅₆H₆₄N₄O₁₂Pd₄
• 分子量: 1410.82
• InChiKey: YSXOYIRSQYLTBA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis-palladium-bis (μ-acetato)-3,6-bis(4'-butyloxyphenyl)pyridazine 、 sodium (Z)-4-oxopent-2-en-2-olate 以 四氢呋喃 为溶剂， 生成 3,6-bis(4-butoxybenzene-6-id-1-yl)pyridazine;(Z)-4-oxopent-2-en-2-olate;palladium(2+)
  参考文献：
  名称：

  Doubly cyclopalladated pyridazines: chiral liquid crystals

  摘要：

  The mono and dicyclopalladation of new mesogenic pyridazines and subsequent reaction with beta-diketones yields some novel metallomesogens. The monometallated derivatives have a flat central core. In contrast. the dimetallated derivatives have a sterically induced twist in the molecule that renders them chiral. Smectic A phases are typically exhibited by both the derivatives with transition temperatures in the region of 100-300 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01330-4
• 作为产物：
  描述：

  palladium diacetate 、 3,6-bis(4'-(butyloxy)phenyl)pyridazine 以 甲醇 为溶剂， 生成 bis-palladium-bis (μ-acetato)-3,6-bis(4'-butyloxyphenyl)pyridazine
  参考文献：
  名称：

  Doubly cyclopalladated pyridazines: chiral liquid crystals

  摘要：

  The mono and dicyclopalladation of new mesogenic pyridazines and subsequent reaction with beta-diketones yields some novel metallomesogens. The monometallated derivatives have a flat central core. In contrast. the dimetallated derivatives have a sterically induced twist in the molecule that renders them chiral. Smectic A phases are typically exhibited by both the derivatives with transition temperatures in the region of 100-300 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01330-4