1,3,5-[Cl(CO)(PMe3)3RuCH=CH]3C6H3 | 847749-48-8

• 英文名称: 1,3,5-[Cl(CO)(PMe3)3RuCH=CH]3C6H3
• CAS: 847749-48-8
• 化学式: C₄₂H₉₀Cl₃O₃P₉Ru₃
• 分子量: 1331.51
• InChiKey: CEIBUSYKNYLHOZ-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  1,3,5-[Cl(CO)(PPh3)2RuCH=CH]3C6H3 、 三甲基膦 以 四氢呋喃 为溶剂， 以68%的产率得到1,3,5-[Cl(CO)(PMe3)3RuCH=CH]3C6H3
  参考文献：
  名称：

  Synthesis and Characterization of Trimetallic Ruthenium and Bimetallic Osmium Complexes with Metal−Vinyl Linkages

  摘要：

  Treatment of RuHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3, which reacts with PMe3 to give 1,3,5-[Cl(CO)(PMe3)(3)RuCH=CH](3)C6H3. 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)(2)RuCH=CH](3)C6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh3)(3) with ArCdropCH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3)(3). Reaction of OsHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HCdropC-3,5-[Cl(CO)(PPh3)(3)OsCH=CH](2)C6H3, which reacts with PMe3 to give 1-HCdropC-3,5-[OsCl(CO)(PPh3)(2)(PMe3)OsCH=CH](2)C6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.

  DOI：

  10.1021/om0496939