| 219482-37-8

• CAS: 219482-37-8
• 化学式: C₂₃H₃₄Cu₂N₅O₅*ClO₄
• 分子量: 687.096
• InChiKey: UGPYTJKIHPCRHK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium perchlorate 、 copper(II) acetate monohydrate 、 2,6-bis[(N-methylpiperazin-1-yl)methyl]-4-cyanophenol 以 乙醇 、 水 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis of a new binucleating ligand and its binuclear Cu(II) complex: X-ray crystal structure, spectral and electrochemical properties

  摘要：

  The preparation of a pentadentate binucleating ligand 2,6-bis[(N-methyl piperazin-1-yl)methyl]-4-cyano phenol (HL) is described together with the corresponding acetato bridged Cu(II) complex [Cu2L-(CH3COO)(2)]CO4. Both the ligand and the complex were characterized by elemental analysis and spectral studies. The electro-chemical behavior of the complex is discussed in detail. A Crystal structure analysis shows that the ligand is pentadentate donating two nitrogens as well as a bridging oxygen to each copper. Two acetates bridge the coppers through axial and apical positions to yield square-pyramidal coppers with a distorted square base. Perchlorates occupy interstitial positions. The structure is held in three-dimensional space by electrostatic attractions and Vander Waals forces. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00124-7