| 87173-07-7

• CAS: 87173-07-7
• 化学式: C₃₄H₃₁FeO₂P
• 分子量: 558.44
• InChiKey: AMCVWCHZRORNNE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 溴甲苯 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Stereoselective elaboration of the acyl ligand in (η5-C5H5)Fe(CO)(PPh3)(COCH2R) via the alkylation of the anions [(η5-C5H5)Fe(CO)(PPh3)(COCHR)]Li (R = Me, Et)

  摘要：

  DOI：

  10.1016/s0022-328x(00)98854-5

文献信息

• Stereoselective carbon–carbon bond formation via alkylation of [(η-⁵C₅H₅)Fe(PPh₃)(CO)(COMeCHR)](R = Me,Prⁿ,Ph): X-ray crystal structure of (Z)-[(η⁵-C₅H₅)Fe(PPh₃)(CO)(COMeCHMe)]
  作者：Gordon J. Baird、Stephen G. Davies、Richard H. Jones、Keith Prout、Peter Warner

  DOI：10.1039/c39840000745

  日期：——

  [(η-2C5H5)Fe(PPh3)(CO)(Mthoxycarbene)]+ complexes, prepared either from terminal acetylenes or from the corresponding acyl complexes, are stereoselectively deprotonated, as evidenced by the crystal structure of (Z)-[(η5-C5H5)Fe(PPh3)(CO)(COMeCHMe)], to (Z)-methoxyvinyl complexes which can be stereoselectively alkylated under mild conditions to give elaborated acyl complexes.