dimethyloxalic acid-bis(2-methylphenyl)imidoatenickel(II)dibromide | 860025-15-6

• 英文名称: dimethyloxalic acid-bis(2-methylphenyl)imidoatenickel(II)dibromide
• CAS: 860025-15-6
• 化学式: C₁₈H₂₀Br₂N₂NiO₂
• 分子量: 514.867
• InChiKey: XRZBPKNNLVUGQM-SUGRRRODSA-L

反应信息

• 作为产物：
  描述：

  dibromo(1,2-dimethoxyethane)nickel(II) 、 dimethyloxalic acid-bis(2-methylphenyl)imidoate 以 N,N-二甲基甲酰胺 为溶剂， 以95%的产率得到dimethyloxalic acid-bis(2-methylphenyl)imidoatenickel(II)dibromide
  参考文献：
  名称：

  Nitrogen- and phosphorus-coordinated nickel(II) complexes as catalysts for the oligomerization of ethylene

  摘要：

  Nitrogen- and phosphorus-coordinated nickel(II) complexes 1 and 2 are active precatalysts together with the cocatalyst MAO for the oligomerization of ethylene mainly favoring the production of butenes. The nickel(II) complex 2b reveals a good selectivity at higher ethylene pressure for the production of 1-butene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.11.015