[RuCl2(η6-1,3,5-trimethylbenzene)(dimethylamino)] | 1337924-31-8

• 英文名称: [RuCl2(η6-1,3,5-trimethylbenzene)(dimethylamino)]
• CAS: 1337924-31-8
• 化学式: C₁₁H₁₉Cl₂NRu
• 分子量: 337.255
• InChiKey: UFSBCDTVFQAAJF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(mesitylene)ruthenium(II) dimer 、 二甲胺 以 四氢呋喃 为溶剂， 以89%的产率得到[RuCl2(η6-1,3,5-trimethylbenzene)(dimethylamino)]
  参考文献：
  名称：

  Arene–Ruthenium(II) Complexes Containing Inexpensive Tris(dimethylamino)phosphine: Highly Efficient Catalysts for the Selective Hydration of Nitriles into Amides

  摘要：

  The catalytic hydration of nitriles into amides, in water under neutral conditions, has been studied using a series of arene-ruthenium(II) derivatives containing the commercially available and inexpensive ligand tris(dimethylamino)phosphine. Among them, best results were obtained with the complex [RuCl2(eta(6)-C6Me6){P(NMe2)(3)}], which selectively provided the desired amides in excellent yields and short times (TOF values up to 11 400 h(-1)). The process was operative with both aromatic, heteroaromatic, aliphatic, and alpha,beta-unsaturated organonitriles and showed a high functional group tolerance. The stability of [RuCl2(eta(6)-C6Me6){P(NMe2)(3)}] in water was evaluated, observing its progressive decomposition into the less-active dimethylamine nithenium(II) complex [RuCl2(eta(6)-C6Me6)(NHMe2)] by hydrolysis of the coordinated P(NMe2)(3) ligand. The X-ray crystal structure determination of the toluene complex [RuCl2(eta(6)-C6H5Me){P(NMe2)(3)}] is also included.

  DOI：

  10.1021/om2006563