[Mn(1,2-di(imino-4'-antipyrinyl)ethane)Cl2] | 381228-64-4

• 英文名称: [Mn(1,2-di(imino-4'-antipyrinyl)ethane)Cl2]
• CAS: 381228-64-4
• 化学式: C₂₄H₂₄Cl₂MnN₆O₂
• 分子量: 554.338
• InChiKey: UZMLKHPPYJOYGF-OXBZONAHSA-L

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 1,2-(diimino-4'-antipyrinyl)ethane 以 丙酮 为溶剂， 以90%的产率得到[Mn(1,2-di(imino-4'-antipyrinyl)ethane)Cl2]
  参考文献：
  名称：

  MANGANESE(II) COMPLEXES OF 1,2-DI(IMINO-4′-ANTIPYRINYL)ETHANE

  摘要：

  Manganese(IT) complexes of the Schiff base 1,2-di(imino-4 ' -antipyrinyl)-ethane (GA) have been synthesized and characterized by elemental analyses, electrical conductance in non-aqueous solvents, infrared and electronic spectra as well as magnetic susceptibility measurements. The complexes have the general formulae [Mn(GA)X-2] (X = ClO4, NO3, Cl, Br or I). GA acts as a neutral tetradentate ligand coordinating through both carbonyl oxygens and both azomethine nitrogens. Both anions are coordinated to the metal ion and the perchlorate as well as nitrate ions are monodentate. A high-spin octahedral geometry is assigned around Mn(II) in all of these complexes.

  DOI：

  10.1081/sim-100106861