(1-N-7-azaindolyl-1,3-butanedionato)2AlCH3 | 383367-29-1

• 英文名称: (1-N-7-azaindolyl-1,3-butanedionato)2AlCH3
• CAS: 383367-29-1
• 化学式: C₂₃H₂₁AlN₄O₄
• 分子量: 444.426
• InChiKey: FRTAQUASZPCTPU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  三甲基铝 、 1-N-7-azaindolyl-1,3-butanedione 以 甲苯 为溶剂， 以89%的产率得到(1-N-7-azaindolyl-1,3-butanedionato)2AlCH3
  参考文献：
  名称：

  Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh2(acac-azain) and Al(CH3)(acac-azain)2, acac-azain=1-N-7-azaindolyl-1,3-butanedionato

  摘要：

  A novel blue luminescent ligand, 1-N-7-azaindolyl-1,3-butanedione (acac-azainH), has been synthesized and characterized structurally. The acac-azainH has a diketone structure in the solid state. The diketone form of acac-azainH is also dominant in solution. The acac-azainH molecule reacts readily with BPh3 and Al(CH3)(3) to form chelate complexes BPh2(acac-azain) (1) and Al(CH3)(acac-azain)(2) (2), respectively. The structure of 1 was determined by a single-crystal X-ray diffraction analysis. The acac-azainH molecule and compounds 1 and 2 are all blue luminescent but the luminescent efficiency is poor. In solution, compound 2 appears to exist in two isomeric forms. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01017-8