2,6-dimethyl-5-hydro-s-indacenide-Rh(I)(cyclooctadiene) | 260061-10-7

• 英文名称: 2,6-dimethyl-5-hydro-s-indacenide-Rh(I)(cyclooctadiene)
• CAS: 260061-10-7
• 化学式: C₂₂H₂₅Rh
• 分子量: 392.346
• InChiKey: BBDUDAZRHLOGPF-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 2,6-dimethyl-5-hydro-s-indacenide-Rh(I)(cyclooctadiene) 在 KH 作用下， 以 四氢呋喃 为溶剂， 以>=99的产率得到s-indacene-diide-bis[Rh(I)(cyclooctadiene)]
  参考文献：
  名称：

  Synthesis, properties and reactivity of mononuclear Rh(I) and Ir(I) complexes of s- and as-hydroindacenide ligands

  摘要：

  The monometallic complexes with Rh(COD) and Ir(COD) of 1,5- and 1,7-dihydro-s-indacene, 2,6-dimethyl-1,5-dihydro-s-indacene and 2,7-dimethyl-1,6-dihydro-as-indacene have been synthesized and characterized spectroscopically and structurally. Deprotonation and further complexation of these compounds afforded mixtures of syn and anti homobimetallic isomers. The syn/anti ratio depends on the structure of the ion pairs of the salt and on the s or as geometry of the bridging ligand. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00522-7
• 作为产物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 2,6-Dimethyl-1,5-dihydro-s-indacene 在 KH 作用下， 以 四氢呋喃 为溶剂， 生成 2,6-dimethyl-5-hydro-s-indacenide-Rh(I)(cyclooctadiene)
  参考文献：
  名称：

  Synthesis, properties and reactivity of mononuclear Rh(I) and Ir(I) complexes of s- and as-hydroindacenide ligands

  摘要：

  The monometallic complexes with Rh(COD) and Ir(COD) of 1,5- and 1,7-dihydro-s-indacene, 2,6-dimethyl-1,5-dihydro-s-indacene and 2,7-dimethyl-1,6-dihydro-as-indacene have been synthesized and characterized spectroscopically and structurally. Deprotonation and further complexation of these compounds afforded mixtures of syn and anti homobimetallic isomers. The syn/anti ratio depends on the structure of the ion pairs of the salt and on the s or as geometry of the bridging ligand. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00522-7