2-((l4-boraneyl)(methyl)-l5-phosphaneyl)propan-2-ol | 190836-01-2

• 英文名称: 2-((l4-boraneyl)(methyl)-l5-phosphaneyl)propan-2-ol
• CAS: 190836-01-2
• 化学式: C₄H₁₄BOP
• 分子量: 119.939
• InChiKey: GXDYVYTVEPPQIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  methylphosphine borane 、 丙酮 以 苯 为溶剂， 以30%的产率得到2-((l4-boraneyl)(methyl)-l5-phosphaneyl)propan-2-ol
  参考文献：
  名称：

  PH bond activation of primary phosphine-boranes: Access to α-hydroxy and α,α′-dihydroxyphosphine-borane adducts by uncatalyzed hydrophosphination of carbonyl derivatives

  摘要：

  Primary P-phenyl and P-methyl phosphine-boranes 1 and 2 are prepared by complexation of the free phosphines with BH3 . SMe2. They are stable and can be purified by distillation. Under basic conditions, they lead selectively to secondary alkylphosphine-boranes and under neutral conditions to the corresponding mono- and bis-hydroxyphosphine-boranes 5 and 6. All these new compounds are purified by chromatography on silica gel. A competitive hydroboration induced by the decomplexation of BH3 is observed as a minor process. Conditions for the decomplexation of phosphine-borane adducts are presented.

  DOI：

  10.1016/s0022-328x(96)06640-5