| 1400681-87-9

• CAS: 1400681-87-9
• 化学式: C₈₈H₁₁₆Li₄N₄
• 分子量: 1257.68
• InChiKey: VHZBFIOTKTZUEV-BJGBTCSCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 air 作用下， 以 正己烷 、 正戊烷 为溶剂， 以87.1%的产率得到(4R,5R)-4,5-ditert-butyl-1-N,2-N-bis[2,6-di(propan-2-yl)phenyl]-4,5-dihydroacenaphthylene-1,2-diimine
  参考文献：
  名称：

  Unique Radical Dearomatization and Two-Electron Reduction of a Redox-Active Ligand

  摘要：

  The syntheses and characterizations of [Li-4][(1,2-di-(tert-butyl)-dpp-BIAN)(2)] (7), (1,2-di-(tertbutyl)-dpp-BIAN) (8), and (1-(tert-butyl)-2-OH-dpp-BIAN) (9) are described. Compound 7 was formed via a radical dearomatization, two-electron reduction pathway that was accompanied by vicinal di-tert-butylation of the BIAN ligand backbone. Oxidation of 7 afforded a dearomatized vicinal di-tert-butyl substituted BIAN ligand (8). An analogous dearomatized vicinal tert-butyl-hydroxy substituted BIAN ligand (9) was also isolated in the course of mechanistic studies related to the formation of 7.

  DOI：

  10.1021/ja307050r
• 作为产物：
  描述：

  叔丁基锂 、 1,2-双-[(2,6-二异丙基苯基)亚氨基]苊 以 正己烷 、 正戊烷 为溶剂， 反应 48.0h， 以87.1%的产率得到
  参考文献：
  名称：

  Unique Radical Dearomatization and Two-Electron Reduction of a Redox-Active Ligand

  摘要：

  The syntheses and characterizations of [Li-4][(1,2-di-(tert-butyl)-dpp-BIAN)(2)] (7), (1,2-di-(tertbutyl)-dpp-BIAN) (8), and (1-(tert-butyl)-2-OH-dpp-BIAN) (9) are described. Compound 7 was formed via a radical dearomatization, two-electron reduction pathway that was accompanied by vicinal di-tert-butylation of the BIAN ligand backbone. Oxidation of 7 afforded a dearomatized vicinal di-tert-butyl substituted BIAN ligand (8). An analogous dearomatized vicinal tert-butyl-hydroxy substituted BIAN ligand (9) was also isolated in the course of mechanistic studies related to the formation of 7.

  DOI：

  10.1021/ja307050r