2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-((2-morpholin-1-yl)ethyl)-4-bora-3a,4a-diaza-s-indacene | 1396318-70-9

• 英文名称: 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-((2-morpholin-1-yl)ethyl)-4-bora-3a,4a-diaza-s-indacene
• CAS: 1396318-70-9
• 化学式: C₂₃H₃₄BF₂N₃O
• 分子量: 417.35
• InChiKey: WOKUOKILOSXYCF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吗啉 、 硼,[3-乙基-5-[1-(4-乙基-3,5-二甲基-2H-吡咯-2-亚基-kN)乙基]-2,4-二甲基-1H-吡咯酸根-kN]二氟-,(T-4)- 、 二溴甲烷 反应 7.0h， 以66%的产率得到2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-((2-morpholin-1-yl)ethyl)-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  A Mannich-Type Reaction at the meso-Methyl Position of the BODIPY Fluorophore

  摘要：

  Treatment of 2,6-diethyl-4,4-difluoro-1,3,5,7,8-pentamethyl-4-bora-3a, 4a-diaza-s-indacene (BODIPY) with secondary amines in dihalomethane resulted in carbon-carbon bond formation at the meso-methyl position of BODIPY via Mannich-type reactions. The resulting modified BODIPY fluorophores possess high fluorescent quantum yields.

  DOI：

  10.1055/s-0031-1290669