| 657414-75-0

• CAS: 657414-75-0
• 化学式: C₁₉H₂₀ClFeN₂O₂
• 分子量: 399.68
• InChiKey: POXMYYQYYZAVTR-RMEZTLRISA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 、 potassium hydroxide 以 氢氧化钾 、 二甲基亚砜 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

  摘要：

  Crystal structure of [Fe(salphen)Cl] (H(2)salphen = N,N'-(1R,2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield mu-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt. (C) 2003 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(03)00311-6
• 作为产物：
  描述：

  三氯化铁 、 N,N'-bis(salicylidene)-2,2-dimethyl-1,3-diaminopropane 以 乙醇 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

  摘要：

  Crystal structure of [Fe(salphen)Cl] (H(2)salphen = N,N'-(1R,2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield mu-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt. (C) 2003 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(03)00311-6