Co2(CO)4(PMe3)2(μ-η2-Me3SiC2CCSiMe3) | 344588-33-6

• 英文名称: Co2(CO)4(PMe3)2(μ-η2-Me3SiC2CCSiMe3)
• 英文别名: Co2(CO)4(trimethylphosphine)2(1,4-bis(trimethylsilyl)butadiyne)
• CAS: 344588-33-6
• 化学式: C₂₀H₃₆Co₂O₄P₂Si₂
• 分子量: 576.608
• InChiKey: CJAWHCOSPLHHCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 Co2(CO)4(PMe3)2(μ-η2-Me3SiC2CCSiMe3) 以 正己烷 为溶剂， 以8%的产率得到[Co2(CO)4(trimethylphosphine)2][Co2(CO)6](1,4-bis(trimethylsilyl)butadiyne)
  参考文献：
  名称：

  Syntheses, structures and electrochemical study of π-acetylene complexes of cobalt

  摘要：

  The preparation and characterisation of the complexes [Co-2(CO)(4)(PMe3)(2)][Co-2(CO)(6)](Me3SiC2C2SiMe3) (4), [Co-2(CO)(4)(dppm)] [Co-2(CO)(6)](Me3SiC2C2H) (5), [Co-2(CO)(4)(dppa)][Co-2(CO)(6)](Me3SiC2C2SiMe3) (6), [Co-2(CO)(4)(dppm)](2) [Co-2(CO)(6)](Me(3)SiC(2)Cdrop CC2C2SiMe3) (7) and [{SiMe3(Co-2(CO)(4)(dppm))C-2}(2)(HCdropC)(1,3,5-C6H3)] (8) are described. An electrochemical study of the complexes 5-8 and of the related [Co-2(CO)(4)(dppm)](2)(Me3SiC2-(CdropC)(2)C2SiMe3) (1), [Co-2(CO)(4)(dppa)](2)(Me3SiC2C2SiMe3) (2) and [{SiMe3(Co-2(CO)(4)(dppm))C-2}(HCdropC)(2)(1,3, 5-C6H3)] (3) is presented by means of the cyclic and square-wave voltammetry techniques. Crystals of 8 suitable for single-crystal X-ray diffraction were grown and the molecular structure of this compound is discussed. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.12.020
• 作为产物：
  描述：

  Co2(CO)5PMe3(μ-η2-Me3SiC2CCSiMe3) 、 三甲基膦 以 甲苯 为溶剂， 以73%的产率得到Co2(CO)4(PMe3)2(μ-η2-Me3SiC2CCSiMe3)
  参考文献：
  名称：

  Alkynyl cobalt complexes. An electrochemical study

  摘要：

  The preparation and characterisation of the complexes Co-2(CO)(5)(PMe3)(mu-eta (2)-Me3SiC2C=CSiMe3) (2) and Co-2(CO)(4)(PMe3)(2)(mu-eta (2)-Me3SiC2C=CSiMe3) (3) are described. A comparative electrochemical study of the complexes Co-2(CO)(6-n)L-n(mu-eta (2)-Me3SiC2C=CSiMe3) (n = 0 (1); n = 1, L = PMe3 (2); n = 2, L = PMe3 (3), PPh2Me (4), dppa (5), dppm (6)) is presented by means of the cyclic and square-wave voltammetry techniques. Substitution of CO by phosphine ligands transforms the Co2C2 redox centre from a readily reducible to an easily oxidisable centre and contributes to the stabilisation of the Go-Co bond increasing the lifetime of the radical cations and anions. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00349-2