[Tl(μ3-2,4-dichlorophenolate)]4 | 1093135-78-4

• 英文名称: [Tl(μ3-2,4-dichlorophenolate)]4
• 英文别名: [Tl(mu.3-dcp)]4
• CAS: 1093135-78-4
• 化学式: C₂₄H₁₂Cl₈O₄Tl₄
• 分子量: 1465.51
• InChiKey: QUMMOEOLNQTUPV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  thallium(I) nitrate 、 2,4-二氯酚 在 氢氧化钾 作用下， 以 水 、 乙腈 为溶剂， 以44%的产率得到[Tl(μ3-2,4-dichlorophenolate)]4
  参考文献：
  名称：

  A novel tetranuclear cubic cage, [Tl4(μ3-dcp)4] {Hdcp=2,4-dichlorophenol}, new short Cl⋯Cl interactions, thermal, fluorescence, structural and solution studies

  摘要：

  The single crystal X-ray analysis of a novel Tl-1 complex of 2,4-dichlorophenol (Hdcp) ligand shows that the complex has a tetranuclear cubic cage as a result of bridging ligands dcp(-) with basic repeating of [Tl(mu(3)-dcp)] units. There are four thallium atoms with similar coordination spheres in the cubic cage. These thallium atoms contain irregular coordination sphere with stereo-chemically active tone pair. The thermal stability of [Tl-4(mu(3)-dcp)(4)] was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The compound [Tl-4(mu(3)-dcp)(4)] is luminescent in the solution state with emission maxima at 397 nm. The results of studies of the stoichiometry and formation of [Tl-4(mu(3)-dcp)(4)] Complex in DMF solution were found to be in support of their solid state stoichiometry. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.06.017