| 508170-35-2

• CAS: 508170-35-2
• 化学式: C₂₆H₃₄FeNOP₂*I
• 分子量: 621.261
• InChiKey: OTWHOKIKWQHOSW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 、 2-diphenylphosphanyl-N-di(propan-2-yl)phosphanylethanamine 在 cyclopentadienyl iron(II) dicarbonyl dimer 作用下， 以 乙腈 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Preparation and coordination chemistry of Ph2P(CH2)nNHPiPr2 (n=2, 3)

  摘要：

  Unsymmetrical diphosphine ligands of the type Ph2P(CH2)(n)NHPPr2i [n = 2 (1), 3 (2)] have been obtained by reacting the appropriate (diphenylphosphino)alkylamine, Ph2P(CH2)(n)NH2 with chlorodi-iso-propylphosphine, in the presence of triethylamine. Reaction of Ph2P(CH2)(2)NHPPr2i with PdCl2(PhCN)(2), PtCl2(PhCN)(2), PtMe2(cod) and PtClMe(cod), NiCl2.6H(2)O and Fe(CO)(2)(eta(5)-C5H5)I gives the corresponding chelate complexes, PdCl2L, PtX2L, NiCl2L and Fe(CO)(eta(5)-C5H5)L. Reaction of Ph2P(CH2)(3)NHPPr2i with PtCl2(PhCN)(2), PtMe2(cod) and PdCl2(PhCN)(2) yields the chelate complexes and reaction with PtClMe(cod) led to a 50:50 mixture of chelate isomers. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01236-6