Ir(C5(CH3)5)η(2)-(Ph2P(Se)NP(Se)Ph2-Se,Se')SCN | 252254-27-6

• 英文名称: Ir(C5(CH3)5)η(2)-(Ph2P(Se)NP(Se)Ph2-Se,Se')SCN
• CAS: 252254-27-6
• 化学式: C₃₅H₃₅IrN₂P₂SSe₂
• 分子量: 927.83
• InChiKey: VFOFQXWQAZTREG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 Ir(C5(CH3)5)η(2)-(Ph2P(Se)NP(Se)Ph2-Se,Se')Cl 以 四氢呋喃 为溶剂， 以70%的产率得到Ir(C5(CH3)5)η(2)-(Ph2P(Se)NP(Se)Ph2-Se,Se')SCN
  参考文献：
  名称：

  The synthesis and crystal structures of the first examples of six-membered inorganic iridacycles containing the [(Ph2PE)2N]− ligand (E=S or Se)

  摘要：

  The reaction of the potassium salt of either imidotetraphenyldithiodiphosphinate (L-1) or imidotetraphenyldiselenodiphosphinate (L-2) with [Cp*IrCl(mu-Cl)](2) in THF yields the complexes Cp*Ir{Ph2P(S)NP(S)Ph-2-S,S'}Cl (1) and Cp*Ir{Ph2P(Se)NP(Se)Ph-2-Se,Se'}Cl (2), respectively. Compounds 1 and 2 can be further converted into a range of new mononuclear species comprising mixed [Cp*,E-3] donor sets by metathetic exchange of the chloro ligand for either thiocyanate or selenocyanate. These are the first examples of neutral monomeric Ir(III) complexes which have this ligand set. All compounds were characterised by a combination of NMR spectroscopy (H-1 and P-31{H-1}), IR spectroscopy, microanalysis and X-ray crystallography. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00351-4