The observation of gas-phase carbon dioxide complex W (CO)5(CO2). Kinetics and bond energy for reaction of CO2 with W(CO)5
摘要:
The complex W(CO)5(CO2) has been observed in the gas phase by time-resolved infrared spectroscopy following 355 nm laser photolysis of W(CO)6 in the presence of CO2. The complex was shown to be in equilibrium with its precursor W(CO)5 at room temperature and the bond energy for binding of CO2 to W(CO)5 was estimated to be 8.2 kcal mol-1.