| 402731-32-2

• CAS: 402731-32-2
• 化学式: C₁₈H₁₅ClFeN₂O
• 分子量: 366.63
• InChiKey: DQCMNPZTVJHPCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三乙基铟 以 甲苯 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Preparation, characterization, electrochemical studies and crystal structure determination of salicylaldehyde–aroylhydrazone, ferrocenyl–aroylhydrazone and salicylaldehyde–ferrocenoylhydrazone complexes of indium

  摘要：

  The reaction of triethylindium with salicylaldehyde-aroylhydrazone, C6H4(o-OH)-CHNNH-C(O)C6H4-X (X =p-H, p-OCH3, p-NO2, m-NO2, o-OH), yields the tetrahydrofuran (THF) adduct of (C14H9N2O2X)(2)InC2H5. With formylferrocenyl-aroylhydrazones C5H5FeC5H4-CHNNH-C(O)C6H4-X (X=p-H, p-OCH3, p-NO2, m-NO2, P-Cl, o-Cl), the diethylindium-hydrazone complex, (C18H14N2OFeX)In(C2H5)(2), was formed. With salicylaldehyde-ferrocenoylhydrazone, C6H4(o-OH)-CHNNH-C(O)C5H4FeC5H5, the monohydrazone complex (C18H15N2O2Fe)In(C2H5)(2) tetrahydrofuran solvate was obtained. The crystal structures of the p-OCH3 derivatives of the first two series of complexes and of the ferrocenoylhydrazone derivative were determined. In the solid state, the three complexes are dimers, containing a set of seven, three and five fused rings, respectively. In every case, it was observed a symmetric anti arrangement of fused rings in relation to a central In2O2 four-membered ring, resulting in a configuration that resembles a chair. Cyclic voltammetric studies on the ferrocenylaroylhydrazone complexes revealed electron transference from the ferrocene group towards the indium atom, while for the salicilaldehyde-ferrocenoyl complex this was not observed. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00961-5