Cp2Mo2(μ-S(CH2)2SH)(μ-SMe)3 | 192637-68-6

• 英文名称: Cp2Mo2(μ-S(CH2)2SH)(μ-SMe)3
• 英文别名: cyclopenta-1,3-diene;methanethiolate;molybdenum(3+);2-sulfanylethanethiolate
• CAS: 192637-68-6
• 化学式: C₁₅H₂₄Mo₂S₅
• 分子量: 556.566
• InChiKey: LZGGEDSLIVFNQE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Mo2Cp2(μ-SMe)3(μ-Cl)] 、 1,2-乙二硫醇 以 四氢呋喃 为溶剂， 以80%的产率得到Cp2Mo2(μ-S(CH2)2SH)(μ-SMe)3
  参考文献：
  名称：

  Reactions of dinuclear and polynuclear complexes. Part 18 substitution reactions of a μ-chloro or a μ-thiolato ligand in the dinuclear cyclopentadienyl molybdenum(III) complex [Cp2Mo2(μ-Cl)(μ-SMe)3]: Crystal structure of [Cp2Mo2(μ-SCH2CH2SH)(μ-SMe)3] · 0.5CH2Cl2

  摘要：

  Thermal reaction of the chloro-bridged complex [Cp2Mo2(mu-CL)(mu-SMe)(3)] 1 with the dithiols HS(CH2)(n)SH (n = 2 or 3) affords the quadruply thio-bridged complexes [Cp2Mo2{mu-S(CH2)(n)SH}(mu-SMe)(3)] where n = 2 (2) or 3 (3). 2 has been shown by X-ray diffraction to contain the mu-eta(1)-dithiolate ligand S-(CH2)(2)SH which bridges an Mo-Mo single bond whose length is 2.606(1)Angstrom. The substitution reaction of the chloro bridge in 1 also occurs with phenylphosphine, H2PPh, giving the mu-phosphido compound [Cp2Mo2(mu-HPPh)(mu-SMe)(3)] 4. In contrast with diphenylphosphine, HPPh2, the thiolate ligand trans to the chloro bridge is replaced by a PPh2 group, giving the new mu-chloro complex [Cp2Mo2(mu-Cl)(mu-PPh2)(mu-SMe)(2)] 5. All new products have been characterized by spectroscopic analyses. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00082-x