[RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)] | 162855-95-0

• 英文名称: [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)]
• CAS: 162855-95-0
• 化学式: C₄₆H₅₂ClO₄P₃Ru
• 分子量: 898.361
• InChiKey: WOGKDHMZFOTJGM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(triphenylphosphine)-rhenium heptahydride 、 [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)] 在 KH 作用下， 以 四氢呋喃 为溶剂， 以56%的产率得到[(CO)(PPh3)2Re(μ-H)3Ru(P(C6H5)3)2(P(O(i)Pr)3)]
  参考文献：
  名称：

  Synthesis of Re-Ru heterobimetallic polyhydride complexes. Study of the influence of ligands bonded to the monometallic precursors on the nature of the isolated binuclear complexes

  摘要：

  The reaction of K[H(6)ReL(2)] with [RuHCl(CO)(PPh(3))(3-x){P(OPri}3)(x)](L(2) = (PMePh(2))(2), dppe,(AsPh(3))(2), or (PPh(3))(2); x = 0, 1 or 2) leads to [L(2)(CO)HRe(mu-H)(3)RuH(PPh(3))(2-y){P(OPri)(3)}(y)](x = 0 or 1, y = 0; x = 2, y = 1(L(2) = PPh(3))) in a first step. Under the reaction conditions most of these complexes react rapidly with the liberated phosphine giving [L(2)(CO)Re(mu-H)(3)Ru(PPh(3))(3-y)-{P(OPri)(3))(y)] (L(2) = (PMePh(2))(2) or dppe, y = 0; L(2) = (PPh(3))(2) y = 1) as the only isolable complexes. The structure of [(PMePh(2))(2)(Co)Re(mu-H)(3)Ru(PPh(3))(3)] has been established by X-ray structure analysis. The complex [(PPh(3))(2)(CO)Re(mu-H)(3)Ru(PPh(3))(2)(P(OPri)(3))] reacts with molecular hydrogen under pressure to generate [L(2)(CO)HRe(mu-H)(3)RuH)PPh(3))(P(OPri)(3)) as the sole product.

  DOI：

  10.1016/0022-328x(94)05181-a
• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 三异丙基亚磷酸酯 以 甲苯 为溶剂， 以85%的产率得到[RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)]
  参考文献：
  名称：

  Synthesis of Re-Ru heterobimetallic polyhydride complexes. Study of the influence of ligands bonded to the monometallic precursors on the nature of the isolated binuclear complexes

  摘要：

  The reaction of K[H(6)ReL(2)] with [RuHCl(CO)(PPh(3))(3-x){P(OPri}3)(x)](L(2) = (PMePh(2))(2), dppe,(AsPh(3))(2), or (PPh(3))(2); x = 0, 1 or 2) leads to [L(2)(CO)HRe(mu-H)(3)RuH(PPh(3))(2-y){P(OPri)(3)}(y)](x = 0 or 1, y = 0; x = 2, y = 1(L(2) = PPh(3))) in a first step. Under the reaction conditions most of these complexes react rapidly with the liberated phosphine giving [L(2)(CO)Re(mu-H)(3)Ru(PPh(3))(3-y)-{P(OPri)(3))(y)] (L(2) = (PMePh(2))(2) or dppe, y = 0; L(2) = (PPh(3))(2) y = 1) as the only isolable complexes. The structure of [(PMePh(2))(2)(Co)Re(mu-H)(3)Ru(PPh(3))(3)] has been established by X-ray structure analysis. The complex [(PPh(3))(2)(CO)Re(mu-H)(3)Ru(PPh(3))(2)(P(OPri)(3))] reacts with molecular hydrogen under pressure to generate [L(2)(CO)HRe(mu-H)(3)RuH)PPh(3))(P(OPri)(3)) as the sole product.

  DOI：

  10.1016/0022-328x(94)05181-a