[(p-cymene)RuCl2]2(1,3-bis(4-pyridyl)ethane)*dichloromethane | 1391359-25-3

• 英文名称: [(p-cymene)RuCl2]2(1,3-bis(4-pyridyl)ethane)*dichloromethane
• CAS: 1391359-25-3
• 化学式: CH₂Cl₂*C₃₂H₄₀Cl₄N₂Ru₂
• 分子量: 881.568
• InChiKey: GQDZHQMMUQJAID-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  1,2-双(4-吡啶基)乙烷 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 以 四氢呋喃 、 甲醇 为溶剂， 生成 [(p-cymene)RuCl2]2(1,3-bis(4-pyridyl)ethane)*dichloromethane
  参考文献：
  名称：

  Dinuclear arene ruthenium dichloro complexes designed for host–guest propensity

  摘要：

  The synthesis and the crystal structures of several wheel-and-axle metal-organic (waamo) complexes are studied. The design of such systems is basically constituted by the binding between two Ru(II)(p-cymene) Cl-2 units (wheels) and an organic spacer (axle), bearing pyridinic and/or cyano functions. Particular attention is given to the solid-state organization of the waamo complexes and to their propensity to create acceptors sites for guest species The inverted piano-stool motif, a characteristic synthon of half-sandwich ruthenium units, is always observed here, generating well defined layers of host molecules. Both polycatenated and host-guest systems were generated in order to achieve a compact packing. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.03.020