cis-{molybdenum(0)(carbonyl)4(piperidine)(P(O-methyl)3)} | 63105-41-9

• 英文名称: cis-{molybdenum(0)(carbonyl)4(piperidine)(P(O-methyl)3)}
• 英文别名: cis-[Mo(CO)4(NHC5H10)(P(OMe)3)]
• CAS: 63105-41-9
• 化学式: C₁₂H₂₀MoNO₇P
• 分子量: 417.207
• InChiKey: YJBVSFBPSVMRCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  cis-{molybdenum(0)(carbonyl)4(piperidine)(P(O-methyl)3)} 、 1,3-Diphenyl-2,4-bis-p-tolyloxy-[1,3,2,4]diazadiphosphetidine 以 二氯甲烷 为溶剂， 以70%的产率得到[Mo(CO)4(P(OMe)3)]2[μ-trans-(PhNP(OC6H4Me-p))]2
  参考文献：
  名称：

  Organometallics of diphosphazanes. Part 10. Dinuclear group 6 metal carbonyl complexes bridged by a cyclodiphosphazane in its cis or trans form

  摘要：

  Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodiphosphazane ligand, [PhNP(OC(6)H(4)Me-p)](2) (L), have been used as synthons to prepare homo- and hetero-bimetallic complexes in which the cyclodiphosphazane bridges the two metal centres in its cis or trans isomeric forms. The dimolybdenum complex [Mo-2(eta(5)-C5H5)(2)(CO)(4)(mu-L)] has also been synthesized. The trends in P-31 NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed.

  DOI：

  10.1039/dt9940002661
• 作为产物：
  描述：

  cis-tetracarbonylbis(piperidine)molybdenum 、 三甲氧基磷 生成 cis-{molybdenum(0)(carbonyl)4(piperidine)(P(O-methyl)3)}
  参考文献：
  名称：

  Alyea, Elmer C.; Somogyvari, Arpad, Canadian Journal of Chemistry, 1988, vol. 66, p. 397 - 400

  摘要：

  DOI：

文献信息

• Organometallics of diphosphazanes
  作者：V.Sreenivasa Reddy、S.S. Krishnamurthy、M. Nethaji

  DOI：10.1016/0022-328x(92)88010-g

  日期：1992.10

  The reactions of cyclodiphosphazanes [PhNP(OR)]2 (R = CH2CF3 (1) and C6H4Me-p (2)) with Group 6 metal carbonyl derivatives have been investigated. The stereochemistry of the ligand appears to play a significant role in determining its coordination behaviour. The cyclodiphosphazane 1 (isolated as the trans-isomer) affords the dinuclear complexes 9-11 in which the two metal centres are bridged by the diphosphazane ligand. In contrast the cyclodiphosphazane 2 (isolated as a 3/1 mixture of cis- and trans-isomers) yields the mononuclear complexes 3-7 in which the cyclodiphosphazane is coordinated in the eta1-fashion. The structures of [W(CO4(NHC5H10)(PhNP(OC6H4Me-p))2}] (6) and [Mo(CO)4(NHC5H10)}2mu-[PhNP(OCH2CF3)]2}] (9a) have been determined by X-ray crystallography.
• Krishnamurthy, S. S.; Reddy, V. Sreenivasa; Chandrasekaran, A., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 64, # 1-4, p. 99 - 106
  作者：Krishnamurthy, S. S.、Reddy, V. Sreenivasa、Chandrasekaran, A.、Nethaji, M.

  DOI：——

  日期：——