Ba2(μ-OAc)4(OAc)2Cu4(μ-N,N-dimethylaminoethanolate)4(OH)2 | 1146983-82-5

• 英文名称: Ba2(μ-OAc)4(OAc)2Cu4(μ-N,N-dimethylaminoethanolate)4(OH)2
• CAS: 1146983-82-5
• 化学式: C₂₈H₆₀Ba₂Cu₄N₄O₁₈
• 分子量: 1269.64
• InChiKey: PLSKFPIVTSKNHW-UHFFFAOYSA-F

物化性质

• 熔点：
  95 °C(Solvent: Tetrahydrofuran)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ba2(μ-OAc)4(OAc)2Cu4(μ-N,N-dimethylaminoethanolate)4(OH)2 生成 、 copper(II) oxide
  参考文献：
  名称：

  Low temperature and single-source synthesis of a CuO–Ba2Cu3O5+x composite: Fabrication of thin films and characterization

  摘要：

  A new heterobimetallic, single-source precursor with the formula Ba-2(mu-OAc)(4)(OAc)(2)Cu-4(mu-dmae)(4)(OH)(2) (1) [dmae = N,N-dimethylaminoethanolate and OAc = acetate] has been synthesized by the interaction of Cu(OAc)(2) center dot H2O with Ba(dmae)(2) in toluene for the low temperature deposition of CuO-Ba2Cu3O5+x composite thin films. Complex (1) was characterized by melting point, elemental analysis, FT-IR spectroscopy, mass spectrometry, thermal analysis (TGA) and single crystal X-ray diffraction. Complex (1) crystallizes in the triclinic space group P (1) over bar. A TGA study demonstrated that the complex undergoes controlled thermal decomposition at 400 degrees C to give the CuO-Ba2Cu3O5+x composite. The chemical composition and surface morphology of the deposited mixed oxide thin films were analyzed by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray powder diffraction (XRPD), which support the formation of the pure crystalline CuO-Ba2Cu3O5+x composite with particle sizes ranging from 0.08 to 0.4 mu m. The thickness and voltage-current characteristics of the thin films were determined with a profilometer and a voltmeter using the four-probe method, respectively. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.12.041
• 作为产物：
  描述：

  barium N,N-dimethylaminoethanolate 、 copper(II) acetate monohydrate 以 甲苯 为溶剂， 以70%的产率得到Ba2(μ-OAc)4(OAc)2Cu4(μ-N,N-dimethylaminoethanolate)4(OH)2
  参考文献：
  名称：

  Low temperature and single-source synthesis of a CuO–Ba2Cu3O5+x composite: Fabrication of thin films and characterization

  摘要：

  A new heterobimetallic, single-source precursor with the formula Ba-2(mu-OAc)(4)(OAc)(2)Cu-4(mu-dmae)(4)(OH)(2) (1) [dmae = N,N-dimethylaminoethanolate and OAc = acetate] has been synthesized by the interaction of Cu(OAc)(2) center dot H2O with Ba(dmae)(2) in toluene for the low temperature deposition of CuO-Ba2Cu3O5+x composite thin films. Complex (1) was characterized by melting point, elemental analysis, FT-IR spectroscopy, mass spectrometry, thermal analysis (TGA) and single crystal X-ray diffraction. Complex (1) crystallizes in the triclinic space group P (1) over bar. A TGA study demonstrated that the complex undergoes controlled thermal decomposition at 400 degrees C to give the CuO-Ba2Cu3O5+x composite. The chemical composition and surface morphology of the deposited mixed oxide thin films were analyzed by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray powder diffraction (XRPD), which support the formation of the pure crystalline CuO-Ba2Cu3O5+x composite with particle sizes ranging from 0.08 to 0.4 mu m. The thickness and voltage-current characteristics of the thin films were determined with a profilometer and a voltmeter using the four-probe method, respectively. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.12.041