[Zn7(O)2(3-(1,8-naphthalimido)propanoic acid-H)10(DMF)2] | 1429125-41-6

• 英文名称: [Zn7(O)2(3-(1,8-naphthalimido)propanoic acid-H)10(DMF)2]
• 英文别名: [Zn₇(O)₂(3-(1,8-naphthalimido)propanoic acid-H)₁₀(DMF)₂]
• CAS: 1429125-41-6
• 化学式: C₁₅₆H₁₁₄N₁₂O₄₄Zn₇
• 分子量: 3318.41
• InChiKey: FCAOFFMGEUCIFI-UHFFFAOYSA-D

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Zn7(O)2(3-(1,8-naphthalimido)propanoic acid-H)10(DMF)2] 以 neat (no solvent, solid phase) 为溶剂， 生成 N,N-二甲基甲酰胺 、 zinc(II) oxide
  参考文献：
  名称：

  Heptanuclear zinc carboxylate complex: New supramolecular building unit and unique supramolecular architecture

  摘要：

  The reaction of the bifunctional ligand (1,8-naphthalimido)propanoate (L-C2(-)), containing a carboxylate group for metal bonding and a 1,8-naphthalimide group for pi center dot center dot center dot pi stacking interactions, with Zn(O2CCH3)(2)(H2O)(2) yields a novel heptanuclear complex [Zn-7(O)(2)(L-C2)(10)(DMF)(2)]. In the solid-state structure, a central zinc(II) cation is linked to six terminal zinc(II) cations by ten bridging carboxylate ligands and two mu(4)-O ions forming a vertex shared bitetrahedron, a new type of secondary building unit (SBU). The heptanuclear units are organized into a complex three-dimensional architecture by pi center dot center dot center dot pi stacking interactions of the 1,8-naphthalimide groups. Eight of the naphthalimide rings on each heptanuclear unit form pi center dot center dot center dot pi stacking interactions with rings on eight adjacent units generating a unique "single linked" three-dimensional architecture. The TGA data indicate this structure is robust and luminescent studies show the solid emits in the green region. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.011
• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 N,N-二甲基甲酰胺 、 3-(1,3-二氧代-1H-苯并[De]异喹啉-2(3H)-基)丙酸 在 吡啶 、 potassium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 2.0h， 以0.345 g的产率得到[Zn7(O)2(3-(1,8-naphthalimido)propanoic acid-H)10(DMF)2]
  参考文献：
  名称：

  Heptanuclear zinc carboxylate complex: New supramolecular building unit and unique supramolecular architecture

  摘要：

  The reaction of the bifunctional ligand (1,8-naphthalimido)propanoate (L-C2(-)), containing a carboxylate group for metal bonding and a 1,8-naphthalimide group for pi center dot center dot center dot pi stacking interactions, with Zn(O2CCH3)(2)(H2O)(2) yields a novel heptanuclear complex [Zn-7(O)(2)(L-C2)(10)(DMF)(2)]. In the solid-state structure, a central zinc(II) cation is linked to six terminal zinc(II) cations by ten bridging carboxylate ligands and two mu(4)-O ions forming a vertex shared bitetrahedron, a new type of secondary building unit (SBU). The heptanuclear units are organized into a complex three-dimensional architecture by pi center dot center dot center dot pi stacking interactions of the 1,8-naphthalimide groups. Eight of the naphthalimide rings on each heptanuclear unit form pi center dot center dot center dot pi stacking interactions with rings on eight adjacent units generating a unique "single linked" three-dimensional architecture. The TGA data indicate this structure is robust and luminescent studies show the solid emits in the green region. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.011