ferrocene-1,1'-bis(2,4-dioxo-butanoic acid ethylester) | 36683-52-0

• 英文名称: ferrocene-1,1'-bis(2,4-dioxo-butanoic acid ethylester)
• 英文别名: ferrocene-1,1'-bis(2,4-dioxobutanoic acid ethylester)；Ferrocen-1,1'-bis(3-ethoxy-propan-1,3-dion)
• CAS: 36683-52-0
• 化学式: C₂₂H₂₂FeO₈
• 分子量: 470.259
• InChiKey: NJEDXPHPYFSNOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ferrocene-1,1'-bis(2,4-dioxo-butanoic acid ethylester) 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  1-Ethoxycarbonyl-3-ferrocenyl-propan-1,3-dion und Ferrocen-1,1'bis(2,4-dioxobutansäureethylester) als Liganden für Übergangsmetallionen. Kristallstruktur von Bis(1-ethoxycarbonyl-3-ferrocenyl-propan-1,3dionato)kupfer(II)

  摘要：

  The ligands 1-ethoxycarbonyl-3-ferrocenyl-propane-1,3-dion and ferrocene-1,1'-bis(2,4-dioxo-butanoic acid ethylester) have been prepared by reaction of acetylferrocene or 1,1'-diacetylferrocene and diethyl oxalate. They yield neutral chelates with Cu-II, Ni-II, Zn-II, Co-II, and Mn-II. The acid dissociation constants of the ligands and the stability constants of their metal complexes including Fe-II complexes are reported. The structure of bis(1-ethoxycarbonyl-3-ferrocenyl-propane-1,3-dionato)copper(II) was determined by Xray structure analysis. A cis arrangement with a nearly square planar coordination sphere at the Cu atom is found.

  DOI：

  10.1002/(sici)1521-3749(199911)625:11<1912::aid-zaac1912>3.0.co;2-c
• 作为产物：
  描述：

  1,1'-diacetylferrocene 、 草酸二乙酯 在 tBuOK 作用下， 以 甲苯 为溶剂， 以77%的产率得到ferrocene-1,1'-bis(2,4-dioxo-butanoic acid ethylester)
  参考文献：
  名称：

  1-Ethoxycarbonyl-3-ferrocenyl-propan-1,3-dion und Ferrocen-1,1'bis(2,4-dioxobutansäureethylester) als Liganden für Übergangsmetallionen. Kristallstruktur von Bis(1-ethoxycarbonyl-3-ferrocenyl-propan-1,3dionato)kupfer(II)

  摘要：

  The ligands 1-ethoxycarbonyl-3-ferrocenyl-propane-1,3-dion and ferrocene-1,1'-bis(2,4-dioxo-butanoic acid ethylester) have been prepared by reaction of acetylferrocene or 1,1'-diacetylferrocene and diethyl oxalate. They yield neutral chelates with Cu-II, Ni-II, Zn-II, Co-II, and Mn-II. The acid dissociation constants of the ligands and the stability constants of their metal complexes including Fe-II complexes are reported. The structure of bis(1-ethoxycarbonyl-3-ferrocenyl-propane-1,3-dionato)copper(II) was determined by Xray structure analysis. A cis arrangement with a nearly square planar coordination sphere at the Cu atom is found.

  DOI：

  10.1002/(sici)1521-3749(199911)625:11<1912::aid-zaac1912>3.0.co;2-c