chloro(N-methyldiethanolateamine)(η5-pentamethylcyclopentadienyl)titanium | 385831-25-4

• 英文名称: chloro(N-methyldiethanolateamine)(η5-pentamethylcyclopentadienyl)titanium
• CAS: 385831-25-4
• 化学式: C₁₅H₂₆ClNO₂Ti
• 分子量: 335.71
• InChiKey: OOMFAHCMMOFMDT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (五甲基环戊二烯基)三氯化钛(IV) 、 N-甲基二乙醇胺 在 NEt₃ 作用下， 以 二氯甲烷 为溶剂， 以90%的产率得到chloro(N-methyldiethanolateamine)(η5-pentamethylcyclopentadienyl)titanium
  参考文献：
  名称：

  Synthesis, characterization, and catalytic activities in syndiospecific polymerization of styrene for half-sandwich titanium complexes with non-Cp tridentate dianionic ligands MeN(CH2CR2O−)2

  摘要：

  New half-titanocenes, Cp*TiCl[(OCR(2)CH(2))NMe(CH(2)CR(2)' O)] [R,R ' = H (1), R,R ' = Me, H, (2), R,R ' = Me (3)], were prepared from Cp*TiCl(3) (4) with the corresponding alcohols in the presence of triethylamine. X-ray analysis shows that 1 has slightly distorted trigonal bipyramidal geometry around Ti. These complexes exhibited moderate catalytic activities for syndiospecific styrene polymerization in the presence of MAO and the activity increased in the order: 2 > 1 > 4 > 3 (at 50 degrees C), 1 > 2 > 4 > 3 (at 70 degrees C and 90 degrees C). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.02.005

文献信息

• New half-sandwich metallocene catalysts for polyethylene and polystyrene
  作者：Youngjo Kim、Yonggyu Han、Youngkyu Do

  DOI：10.1016/s0022-328x(01)01105-6

  日期：2001.9

  A new type of half-sandwich metallocene catalysts for the polymerization of ethylene and styrene, Cp*MCl(DEA-R) (DEA = (OCH2CH2)(2)N, R = Me, M = Ti (1); R = Me M = Zr (2); R = n-Bu, M = Ti (3)), was prepared by the reaction of corresponding N-alkyl-N,N-diethanolamine with Cp*MCl3 in the presence of triethylamine. Compounds 1-3 are slightly air-sensitive and thermally unstable. All catalyst systems show moderate activities in ethylene polymerization and especially the 2/MMAO system gives PE with broad molecular weight distribution at all polymerization temperatures. In addition, 1/MMAO and 3/MMAO show fairly good activities in sPS polymerization in the order 3/MMAO > 1/MMAO. (C) 2001 Elsevier Science B.V. All rights reserved.