[(W(CO)5)2(p-Ph2BiC6H4BiPh2)] | 244218-29-9

• 英文名称: [(W(CO)5)2(p-Ph2BiC6H4BiPh2)]
• CAS: 244218-29-9
• 化学式: C₄₀H₂₄Bi₂O₁₀W₂
• 分子量: 1450.29
• InChiKey: FPZQNGUSDXZQKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-二溴苯 在 BuLi 、 THF 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 生成 [(W(CO)5)2(p-Ph2BiC6H4BiPh2)]
  参考文献：
  名称：

  Metal carbonyl complexes of the ditertiary bismuthine p-Ph2BiC6H4BiPh2 and the effect of coordination upon bismuthine ligand geometry

  摘要：

  Complexes of the type [M(CO)(5)(p-Ph2BiC6H4BiPh2)] and [{M(CO)(5)}(2)(p-Ph2BiC6H4BiPh2)] (M = Cr or W) have been prepared and characterised by chemical analysis,H-1- and C-13{H-1}-NMR and IR spectroscopies. The crystal structure of p-Ph2BiC6H4BiPh2 is reported. The reaction of [CpFe(CO)(2)(THF)](+) with p-Ph2BiC6H4BiPh2 in refluxing CH2Cl2 results in cleavage of one Bi-C bond to form [CpFe(CO)(2)(BiPh3)](+) identified by an X-ray study. A survey of BiPh3 and its compounds has established that the C-Bi-C angles increase upon complex formation. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00134-5